Citation: Lotfia El Majdoub, LI Jun, ZHANG Yue-Juan, LI Ni-Li, XU Qing-Hong. Photoelectrode of Polyanilines/n-Si(111) Crystalline: Preparation and Photoelectric Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2257-2264. doi: 10.11862/CJIC.2015.282
-
The self-assembled monolayers (SAMs) of aniline and alkyl substituted anilines grafted on n-Si(111) crystalline surface were prepared in the presence of lauroyl peroxide, and the photoelectrodes of polyanilines/n-Si(111) crystalline were prepared based on polymerizations between the SAMs and anilines. Additionally, the polyanilines with sulfonic acid group (SPANI) substituted n-Si(111) crystalline photoelectrodes were prepared via the above samples to fabricate SPANI/n-Si(111) electrodes (Si-SPANIs). Electrochemical studies indicate that the electrode based on 4-bromoaniline (Si-PANI) is better than that of 4-ethynylaniline (Si-C=C-PANI), and the electrode from 4-vinylaniline (Si-C-C-PANI) is the poorest. In addition, anion ring substitution is important in promoting photoelectric conversion of the electrodes. An electrode with high photocurrent density of 15.4 mA·cm-2 and photoelectric transformation efficiency of 13% was obtained.
-
-
[1]
[1] Alex S, IonkinBM F, Carroll A F, et al. ACS Appl. Mater. Interfaces, 2011,3:606-611
-
[2]
[2] Linford M R, ChidseyC E D. J. Am. Chem. Soc., 1993,115: 12631-12632
-
[3]
[3] Xu Q H, Zhao Y X, Wei Y B, et al. Surf. Sci., 2007,601: 1709-1715
-
[4]
[4] Jaiswal M, Menon R. Polym. Int., 2006,55(12):1371-1384
-
[5]
[5] Nils B, BrauerS S, DrabbelsM, et al. J. Phys. Chem. Lett., 2011,2(13):1563-1566
-
[6]
[6] Shao L, Jeon J W, LutkenhausJ L. Chem. Mater., 2012,24 (1):181-189
-
[7]
[7] BurroughesJ H, Bradley D D C, Holmes A B, et al. Nature, 1990,347:539-541
-
[8]
[8] Ferreira M, Pinto M F, Neves I C. Chem. Eng. J., 2015,260: 309-315
-
[9]
[9] Zhou T, Qin Y, Kong Y, et al. Synth. Met., 2015,199:169-173
-
[10]
[10] PlachyT, SedlacikM, Stejskal J, et al. Chem. Eng. J., 2014,256:398-406
-
[11]
[11] Jin H, Wang C, Chen L, et al. J. Hazard. Mater., 2014,279: 156-162
-
[12]
[12] CaiM Q, Wei X Q, Jin M C, et al. J. Chromatogr. A, 2014,1349:24-29
-
[13]
[13] Chen N N, Chen L, Xian Y Z, et al. Talanta, 2015,132:155- 161
-
[14]
[14] Higashi G S, Chabal Y J, Krishnan R, et al. Appl. Phys. Lett., 1990,56(4):504-507
-
[15]
[15] Linford M R, Fenter P, Chidsey C E D, et al. J. Am. Chem. Soc., 1995,117(11):3145-3155
-
[16]
[16] MacDiarmid A G, Chiang J C, Richter A F. Synth. Met., 1987,18:285-290
-
[17]
[17] Zeng X R, Ko T M. J. Polym. Sci. B, 1997,35:1993-2001
-
[18]
[18] XING Qi-Yi(邢其毅), PEI Wei-Wei(裴伟伟), XU Rui-Qiu(徐 瑞秋), et al. Basic Organic Chemistry. 3rd Ed.(基础有机化 学.3版). Beijing: High Education Press, 2005.
-
[19]
[19] Shirahata N, Yonezawa T, Koumoto K, et al. Langmuir, 2003,19(22):9107-9109
-
[20]
[20] Yan J, Tender L M, Lo'pez G P, et al. J. Phys. Chem. B, 2001,105(37):8905-8910
-
[21]
[21] Terry J, Linford M R, Chidsey C E D, et al. Appl. Phys. Lett., 1997,71(8):1056-1058
-
[22]
[22] Ronning C, Feldermann H, Thiele J U, et al. Phys. Rev. B, 1998,58(4):2207-2215
-
[23]
[23] Liu C C, Lee C, Yew T R, et al. Appl. Phys. Lett., 1995,66 (2):168-170
-
[24]
[24] Miotello A, Kelly R, Laidani N. Surf. Coat. Technol., 1994, 65(1/2/3):45-56
-
[25]
[25] Vallon S, Vallier L. ECS Trans., 1997,9:168-177
-
[26]
[26] Kim N Y, Laibinis P E. J. Am. Chem. Soc., 1999,121(30): 7162-7163
-
[27]
[27] Trasferetti B C, Gelamo R V, Davanzo C U, et al. Chem. Mater., 2005,17(18):4685-4692
-
[28]
[28] Scarlete M, McCourt N, Harrod J F, et al. Chem. Mater.,2001, 13(2):655-661
-
[29]
[29] Cédric C, Buron M Q, Lakard B, et al. Electrochim. Acta, 2014,148:53-61
-
[30]
[30] Joseph Y, Besnard I, Vossmeyer T, et al. J. Phys. Chem. B, 2003,107:7406-7413
-
[1]
-
-
[1]
Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
-
[2]
Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
-
[3]
Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
-
[4]
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
-
[5]
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
-
[6]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[7]
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
-
[8]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[9]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[10]
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
-
[11]
Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
-
[12]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[13]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[14]
Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO2/Bi2MoO6 Microsphere Heterojunction for Efficient Photocatalytic CO2 Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
-
[15]
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
-
[16]
Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
-
[17]
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
-
[18]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[19]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[20]
Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(266)
- HTML views(43)