Citation: XU Zhou-Qing, MAO Xian-Jie, ZHANG Xin, CAI Hong-Xin, BIE Hong-Yan, XU Jun, JIA Lei. Syntheses, Crystal Structures and Antitumor Activities of Three Ln(Ⅲ) Complexes with 2-Acetylpyridine Picolinohydrazone[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2249-2256. doi: 10.11862/CJIC.2015.281
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Three lathanide(Ⅲ) complexes, namely [Ln(HL)(NO3)3(CH3OH)2] (Ln=La, 1; Ce, 2) and [Nd(HL)(NO3)3(H2O)]CH3OH(3) (HL=2-acetylpyridine picolinohydrazone), have been isolated and characterized by elemental analyses, infrared spectra and single-crystal X-ray diffraction analyses. The results reveal that in the isostructure complexes 1 and 2, the eleven coordinated Ln(Ⅲ) ion with mono-capped pentagonal antiprism coordination geometry is surrounded by one HL ligand with N2O donor sets, three bidentate nitrate anion and two methanol molecules. In the complex 3, the Nd(Ⅲ) ion is coordinated by one HL ligand with N2O donor sets, three bidentate nitrate anions and one water molecule, thus exhibiting bicapped square antiprism coordination geometry. Furthermore, all the complexes have excellent antitumor activity towards Lovo human colorectal cancer, BGC823 and SGC7901 human gastric cancer cell lines.
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-
[1]
[1] Tsuchida E, Oyaizu K. Coord. Chem. Rev., 2003,237:213-226
-
[2]
[2] Giziroglu E, Aygün M, Sarikurkcu C, et al. Inorg. Chem. Commun., 2013,36:199-205
-
[3]
[3] XIE Qing-Fan (解庆范), GAO Ping-Zhang (高平章), CHEN Yan-Min (陈延民). Chinese J. Inorg. Chem. (无机化学学 报), 2014,30:2382-2388
-
[4]
[4] Tirkey V, Mishra S, Dash H R, et al. J. Organomet. Chem., 2013,732:122-129
-
[5]
[5] Congiu C, Onnis V. Bioorg. Med. Chem., 2013,21:6592- 6599
-
[6]
[6] LIU Hui-Yan (刘会艳), WANG Hai-Ying (王海营), NIU De- Zhong (牛德仲), et al. Chinese J. Inorg. Chem. (无机化学学 报), 2007,23:611-614
-
[7]
[7] Xu Z H, Zhang X W, Zhang W Q, et al. Inorg. Chem. Commun., 2011,14:1569-1571
-
[8]
[8] WANG Hui (王慧), GAN Guo-Qing (甘国庆), QU Yang (瞿阳), et al. Chinese J. Inorg. Chem. (无机化学学报), 2012, 28:1217-1221
-
[9]
[9] Hao Z Y, Liu Q W, Xu J, et al. Chem. Pharm. Bull., 2010,58:1306-1312
-
[10]
[10] SONG Yu-Ming (宋玉民), LI Wen-Juan (李文娟), YANG Mei-Ling (杨美玲). Chinese J. Inorg. Chem. (无机化学学 报), 2014,30:1087-1096
-
[11]
[11] Ma T L, Xu J, Wang Y, et al. J. Inorg. Biochem., 2014,144: 38-46
-
[12]
[12] Sheldrick G M. SHELXL97, Program for the Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
-
[13]
[13] Arauzo A, Lazarescu A, Shova S, et al. Dalton Trans., 2014, 43:12342-12356
-
[14]
[14] Cui Z N, Li Y, Ling Y, et al. Eur. J. Med. Chem., 2010,45: 5576-5584
-
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