Citation: ZHANG Su-Wei, ZHANG Bo-Ping, LI Shun, ZHU Li-Feng, ZHANG Yu-Qiao. Theoretical Study of the Optical Properties of Noble Metal Nano-Particles Dispersed Composite Films[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2135-2142. doi: 10.11862/CJIC.2015.280 shu

Theoretical Study of the Optical Properties of Noble Metal Nano-Particles Dispersed Composite Films

1.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: ZHANG Bo-Ping,
Received Date: 3 April 2015
Available Online: 6 September 2015
Fund Project: 国家自然科学基金(No.51472026,51272023) (No.51472026,51272023)高等学校博士学科点专项科研基金(No.20130006110006)资助项目。 (No.20130006110006)

The optical absorption spectra of the nano-composite films dispersed by Ag, Au and Cu nano-particles were simulated by the classical Mie theory. It was found that the optical absorption spectra exhibit surface plasmon resonance (SPR) absorption peaks in visible region. The positions and intensities of the SPR absorption peaks are strongly affected by the real part (ε_m1) and imaginary part (ε_m2) of dielectric constant of metal and refractive index (n_s) of dielectric. The SPRabsorption position in visible region of the composite film is strongly dependent on n_s rather than ε_m1 and ε_m2. The simulated optical absorption spectra of the composite films dispersed by Ag, Au and Cu by Mie theory in this study are in good agreement with the reported experiment results, especially showing a close SPR peak positions to each other.
- Mie theory;nano-composite film;surface plasmon resonance;refractive index
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沈阳化工大学材料科学与工程学院沈阳 110142