Citation: XIE Peng-Cheng, HUANG Jie. Visible-Light Photocatalytic Properties of Ti1-xVxO2 Films with Dominant {211} Facets Deposited at Room Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2197-2204. doi: 10.11862/CJIC.2015.279
-
Ti1-xVxO2 films with dominant {211} facets were deposited by direct current reactive magnetron sputtering with Ti and Vtargets (99.99% purity) at room temperature. We study the composition, crystal structure and visible-light photocatalytic properties of the films as a function of power of Vtarget. The results showed that crystal phase of Ti1-xVxO2 films was anatase with (211) preferred orientation, but the films deposited at different power of Vtarget had different crystallinities. With the increase of power of Vtarget, the relative contents of Velement increased gradually, meanwhile, crystal grain and deposition rate also increased. In addition, the surface roughness of the film had a maximum value when the power of Vtarget was 150 W. The addition of Velement gives rise to the band gap of TiO2 films narrowing down. As a result, the optical absorption edge of the Ti1-xVxO2 films shifts towards visible-light zone, improving the visible-light photocatalytic activity of the films. When the power of Vtarget came to 150 W, the value of band gap of the Ti1-xVxO2 film was about 2.82 eV, and the film degraded ~80% RhBdyes after 2 h visible-light irradiation. This can be attributed to the synergistic effect of narrow band gap, high energy facet {211}, and high crystallinity.
-
-
[1]
[1] Fujishima A, Honda K. Nature, 1972,238:37-38
-
[2]
[2] Linsebigler A L, Lu G Q, Yates J T. Chem. Rev., 1995,95 (3):735-758
-
[3]
[3] Hoffmann M R, Martin S T, Choi W Y, et al. Chem. Rev., 1995,95(1):69-96
-
[4]
[4] Chen X, Mao S S. Chem. Rev., 2007,107(7):2891-2959
-
[5]
[5] Chen H H, Nanayakkara C E, Grassian V H. Chem. Rev., 2012,112(11):5919-5948
-
[6]
[6] Cromer D T, Herrington K. J. Am. Chem. Soc., 1955,77(18): 4708-4709
-
[7]
[7] Bokhimi X, Morales A, Aguilar M, et al. Int. J. Hydrogen Energy, 2001,26(12):1279-1287
-
[8]
[8] QIN Wei(秦纬), LIU Jian-Jun(刘建军), ZUO Sheng-Li (左胜利), et al. J. Inorg. Mater. (无机材料学报), 2007,22 (5):931-936
-
[9]
[9] Sumita T, Otsuka H, Kubota H, et al. Nucl. Instrum. Methods Phys. Res., Sect. B, 1999,148(1-4):758-761
-
[10]
[10] Sato S. Chem. Phys. Lett., 1986,123(1/2):126-128
-
[11]
[11] Galinska A, Walendziewski J. Energy Fuels, 2005,19(3): 1143-1147
-
[12]
[12] Nowotny J, Sorrell C C, Bak T, et al. Sol. Energy, 2005,78 (5):593-602
-
[13]
[13] Yang H G, Sun C H, Qiao S Z, et al. Nature, 2008,453 (7195):638-641
-
[14]
[14] Han X G, Kuang Q, Jin M S, et al. J. Am. Chem. Soc., 2009,131(9):3152-3153
-
[15]
[15] Yu J G, Qi L F, Jaroniec M. J. Phys. Chem. C, 2010,114 (30):13118-13125
-
[16]
[16] Wu K R, Yeh C W, Hung C H, et al. J. Nanosci. Nanotechnol., 2009,9(6):3433-3440
-
[17]
[17] Wu K R, Yeh C W, Hung C H, et al. J. Nanosci. Nanotechnol., 2010,10(2):1057-1064
-
[18]
[18] Wang C, Hu Q Q, Huang J Q, et al. Int. J. Hydrogen Energy, 2014,39(5):1967-1971
-
[19]
[19] Romero L, Piccirillo C, Castro P M L, et al. Chem. Vap. Deposition, 2015,21(1/2/3):63-70
-
[20]
[20] Ali A, Ruzybayev I, Yassitepe E, et al. J. Phys. Chem. C, 2013,117(38):19517-19524
-
[21]
[21] Ren W J, Ai Z H, Jia F L, et al. Appl. Catal., B, 2007,69 (3/4):138-144
-
[22]
[22] Wang H, Lewis J P. J. Phys.: Condens. Matter., 2005,17(21): 209-213
-
[23]
[23] HE Jing(何静), JIANG Wei-Hui(江伟辉), YU Yun(于云), et al. J. Inorg. Mater. (无机材料学报), 2005,20(3):713-719
-
[24]
[24] Wang Y, Doren D J. Solid State Commun., 2005,136(3):142-146
-
[25]
[25] CHEN Xi-Ming(陈喜明), JIANG Xin(蒋新). J. Zhejiang Univ. (浙江大学学报), 2006,40(1):145-148
-
[26]
[26] LIU Huan(刘欢), GONG Shu-Ping(龚树萍), LIU Jian-Qiao (刘剑桥), et al. J. Func. Mater. (功能材料), 2011,42(11): 2017-2020
-
[27]
[27] ZHANG Xiao-Yong(张晓勇), CHAO Ming-Ju(晁明举), LIANG Er-Jun(梁二军), et al. J. Inorg. Mater. (无机材料学 报), 2009,24(1):34-38
-
[28]
[28] Weiser H B, Milligan W O. J. Phys. Chem., 1934,38(4):513-519
-
[29]
[29] Wen C Z, Jiang H B, Qiao S Z, et al. J. Mater. Chem., 2011,21(20):7052-7061
-
[30]
[30] Jeong B S, Norton D P, Budai J D, et al. Thin Solid Films, 2004,446(1):18-22
-
[31]
[31] Klug H P, Alexander L E. X-Ray Diffraction Procedures: For Polycrystalline and Amorphous Materials. New York: Wiley-Interscience, 1974:87
-
[32]
[32] LAI Fa-Chun(赖发春), LIN Li-Mei(林丽梅), QU Yan(瞿燕). Acta Photonica Sin. (光子学报), 2006,35(10):1551-1554
-
[33]
[33] Al-Ahmad A Y. Opt. Spectrosc., 2012,113(2):197-203
-
[34]
[34] Mardare D, Tasca M, Delibas M, et al. Appl. Surf. Sci., 2000,156(1/2/3/4):200-206
-
[35]
[35] Tang H, Prasad K, Sanjines R, et al. J. Appl. Phys., 1994,75(4):2042-2047
-
[36]
[36] Zheng J Y, Bao S H, Guo Y, et al. ACS Appl. Mater. Interfaces, 2014,6(8):5940-5946
-
[37]
[37] Asanuma T, Matsutani T, Liu C, et al. J. Appl. Phys., 2004, 95(11):6011
-
[38]
[38] Watanabe T, Takizawa T, Honda K. J. Phys. Chem., 1977,81(19):1845-1851
-
[1]
-
-
[1]
Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
-
[2]
Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
-
[3]
Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H2O2 Production and Cr(VI) Reduction over a Hierarchical Ti3C2/In4SnS8 Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
-
[4]
Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
-
[5]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[6]
Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
-
[7]
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
-
[8]
Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu2O/Bi2MoO6 Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
-
[9]
Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO2 cycloaddition over W18O49/NH2-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
-
[10]
Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
-
[11]
Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C3N4/Ti3C2Tx Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
-
[12]
Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO2/Bi2MoO6 Microsphere Heterojunction for Efficient Photocatalytic CO2 Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
-
[13]
Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
-
[14]
Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H2O and Its Intermediates on Electron-Deficient Mn(3+δ)+ for Efficient Photocatalytic H2O2 Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
-
[15]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[16]
Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb2O6/Nitrogen-Enriched C3N5 S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
-
[17]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[18]
Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
-
[19]
Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
-
[20]
Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(177)
- HTML views(12)