Citation: HANG Cheng, LU Zhi-Yong, MENG Fei, JIANG Jing-Jing, BAI Jun-Feng. A Microporous 3D MOF Constructed from an Acylamide Tetracid Ligand: Effective Reversible Iodine Adsorption Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2103-2110. doi: 10.11862/CJIC.2015.276
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Amicroporous 3D MOF, [Cu5(L)2(H2O)5] (1) (H4L=5,5'-((1H-pyrazole-3,5-dicarbonyl)bis(azanediyl))diisophthalic)) with acylamide-functionalized and π-electron walls in its structure was synthesized and characterized. Topological analysis reveals 1 is of 3,3,4,4,6-c net and its porosity was tested by N2 and CO2 gas adsorption. Meanwhile, 1 can serve as a good host for encapsulating I2 (1.94 mmol·g-1, RT) and exhibits an outstanding performance in reversible adsorption of iodine molecules.
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