Citation: YANG Xiao-Xun, LENG Ji-Dong, LIU Jun-Liang, JIA Jian-Hua, TONG Ming-Liang. Synthesis, Structures and Magnetic Properties of Two Tetranuclear and Decanuclear Manganese Clusters Bearing the Multidentate Schiff-Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1831-1838. doi: 10.11862/CJIC.2015.260 shu

Synthesis, Structures and Magnetic Properties of Two Tetranuclear and Decanuclear Manganese Clusters Bearing the Multidentate Schiff-Base Ligands

1.
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: JIA Jian-Hua,
Received Date: 29 May 2015
Available Online: 13 July 2015
Fund Project: 国家重点基础研究发展规划("973计划",No.2014CB845602,2012CB821704) ("973计划",No.2014CB845602,2012CB821704)国家自然科学基金(No.21301197,91122032,21371183,91422302) (No.21301197,91122032,21371183,91422302)广东省自然科学基金(S2013020013002) (S2013020013002)以及中央高校基本科研业务费专项资金(14lgpy10)资助项目。 (14lgpy10)

A multidentate salicylaldehyde Schiff-base ligand with {NO₄} donor set, 3, 5-di-tert-butylsalicylaldehyde-trihydroxymethylaminomethane (H₄L), has been synthesized for the first time and characterized by elemental analysis, IR and ¹H NMR. Solution reactions of Mn(ClO₄)₂ or MnCl₂·4H₂O with H₄L in air generated a tetranuclear complex [Mn^III₄(HL)₂(H₂L)₂(MeCN)₄](ClO₄)₂·2MeCN (1) and a decanuclear complex [Mn^III₆Mn^II₄(bz)10(L)₄(H₂O)₂]·10MeCN (2), respectively. X-ray studies reveal that complex 1 crystallizes in triclinic space group P1, while complex 2 crystallizes in orthorhombic space group Aba2. Magnetism data in the temperature range 2~300 K have been carried out, indicating the presence of the antiferromagnetic interaction within 2.
- Schiff-base;manganese cluster;antiferromagnetic interaction
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沈阳化工大学材料科学与工程学院沈阳 110142