Citation: LU Xin-Rong, ZHAO Ying, LIU Jian, LI Cheng-Hui, YOU Xiao-Zeng. Modulation of the Structure and Property of ABX₃ Type Perovskite Photovoltaic Material[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1678-1686. doi: 10.11862/CJIC.2015.257 shu

Modulation of the Structure and Property of ABX₃ Type Perovskite Photovoltaic Material

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: LI Cheng-Hui, YOU Xiao-Zeng,
Received Date: 20 May 2015
Available Online: 20 July 2015
Fund Project: 国家重点基础研究发展规划项目(No.2011CB933300) (No.2011CB933300)国家教育部博士点专项基金(No.20120091130002) (No.20120091130002)江苏省科技支撑计划项目(No.BE2014147-2)等资助。 (No.BE2014147-2)

Perovskite solar cells have been receiving intensive attentions and become a hot research topic in solar cells, due to their high photo-to-electric conversion efficiency, low manufacturing cost and simple fabrication process. In perovskite solar cell, the inorganic-organic hybrid ABX₃ material functions as light absorbing layer as well as charge carrier transporting material. Therefore, the properties of ABX₃ will directly affect the performance of perovskite solar cell. In this paper, we review on the present methods to tune the structure and properties of inorganic-organic hybrid ABX₃ type perovskite photovoltaic material.
- perovskite;solar cell;spectrum;crystal structure;modulation
1. [1]
  [1] Green M A, Ho-Baillie A, Snaith H J. Nat. Photonics, 2014,8(7):506-514
2. [2]
  [2] Hodes G. Science, 2013,342(6156):317-318
3. [3]
  [3] Kim H-S, Im S H, Park N-G. J. Phys. Chem. C, 2014,118(11):5615-5625
4. [4]
  [4] Liu J, Wu Y, Qin C, et al. Energy Environ. Sci., 2014,7(9):2963-2967
5. [5]
  [5] Kojima A, Teshima K, Shirai Y, et al. J. Am. Chem. Soc., 2009,131(17):6050-6051
6. [6]
  [6] Kim H S, Lee C R, Im J H, et al. Sci. Rep., 2012,2:591-597
7. [7]
  [7] Lee M M, Teuscher J, Miyasaka T, et al. Science, 2012,338(6107):643-647
8. [8]
  [8] Burschka J, Pellet N, Moon S J, et al. Nature, 2013,499(7458):316-319
9. [9]
  [9] Liu M, Johnston M B, Snaith H J. Nature, 2013,501(7467):395-398
10. [10]
  [10] Gao P, Grätzel M, Nazeeruddin M K. Energy Environ. Sci., 2014,7(8):2448-2463
11. [11]
  [11] Zhao Y, Zhu K. J. Phys. Chem. Lett., 2014,5(23):4175-4186
12. [12]
  [12] Xing G, Mathews N, Sun S, et al. Science, 2013,342(6156):344-347
13. [13]
  [13] Baikie T, Fang Y, Kadro J M, et al. J. Mater. Chem. A, 2013,1(18):5628
14. [14]
  [14] Mosconi E, Amat A, Nazeeruddin M K, et al. J. Phys. Chem. C, 2013,117(27):13902-13913
15. [15]
  [15] Shockley W, Queisser H J. J. Appl. Phys., 1961,32(3):510-519
16. [16]
  [16] Stranks S D, Eperon G E, Grancini G, et al. Science, 2013, 342(6156):341-344
17. [17]
  [17] Mailoa J P, Bailie C D, Johlin E C, et al. Appl. Phys. Lett., 2015,106(12):121105
18. [18]
  [18] Loper P, Niesen B, Soo-Jin M, et al. IEEE J. Photovolt., 2014,4(6):1545-1551
19. [19]
  [19] YOU Xiao-Zeng(游效曾). Molecular-Based Materials-Opto-Electronic Functional Compounds(分子材料-光电功能化合物). Beijing:Science Press, 2014.
20. [20]
  [20] Stoumpos C C, Malliakas C D, Kanatzidis M G. Inorg. Chem., 2013,52(15):9019-9038
21. [21]
  [21] Li C, Lu X, Ding W, et al. Acta Cryst. Sect. B, 2008,64(6):702-707
22. [22]
  [22] Eperon G E, Stranks S D, Menelaou C, et al. Energy Environ. Sci., 2014,7(3):982
23. [23]
  [23] Pang S, Hu H, Zhang J, et al. Chem. Mater., 2014,26(3):1485-1491
24. [24]
  [24] Koh T M, Fu K, Fang Y, et al. J. Phys. Chem. C, 2014,118(30):16458-16462
25. [25]
  [25] Im J-H, Chung J, Kim S-J, et al. Nanoscale Res. Lett., 2012,7(1):1-7
26. [26]
  [26] McKinnon N K, Reeves D C, Akabas M H. J. Gen. Physiol., 2011,138(4):453-466
27. [27]
  [27] Lee J W, Seol D J, Cho A N, et al. Adv. Mater., 2014,26(29):4991-4998
28. [28]
  [28] Pellet N, Gao P, Gregori G, et al. Angew. Chem. Int. Ed., 2014,53(12):3151-3157
29. [29]
  [29] Jeon N J, Noh J H, Yang W S, et al. Nature, 2015,517(7535):476-480
30. [30]
  [30] Chung I, Song J H, Im J, et al. J. Am. Chem. Soc., 2012, 134(20):8579-8587
31. [31]
  [31] Zhou Y, Garces H F, Senturk B S, et al. Mater. Lett., 2013,110:127-129
32. [32]
  [32] Chung I, Lee B, He J, et al. Nature, 2012,485(7399):486-489
33. [33]
  [33] Shum K, Chen Z, Qureshi J, et al. Appl. Phys. Lett., 2010, 96(22):221903
34. [34]
  [34] Chen Z, Yu C, Shum K, et al. J. Lumin., 2012,132(2):345-349
35. [35]
  [35] Kumar M H, Dharani S, Leong W L, et al. Adv. Mater., 2014,26(41):7122-7127
36. [36]
  [36] Choi H, Jeong J, Kim H-B, et al. Nano Energy, 2014,7:80-85
37. [37]
  [37] Knutson J L, Martin J D, Mitzi D B. Inorg. Chem., 2005,44(13):4699-4705
38. [38]
  [38] Mitzi D B, Wang S, Feild C A, et al. Science, 1995,267(5203):1473-1476
39. [39]
  [39] Mitzi D B, Feild C A, Harrison W T A, et al. Nature, 1994, 369(6480):467-469
40. [40]
  [40] Thiele G, Rotter H W, Schmid K D. Z. Anorg. Allg. Chem., 1987,545(2):148-156
41. [41]
  [41] Mitzi D B. Chem. Mater., 1996,8(3):791-800
42. [42]
  [42] Hao F, Stoumpos C C, Cao D H, et al. Nat. Photonics, 2014, 8(6):489-494
43. [43]
  [43] Hao F, Stoumpos C C, Chang R P H, et al. J. Am. Chem. Soc., 2014,136(22):8094-8099
44. [44]
  [44] Stoumpos C C, Fraser L, Clark D J, et al. J. Am. Chem. Soc., 2015,137(21):6804-6819
45. [45]
  [45] Ogomi Y, Morita A, Tsukamoto S, et al. J. Phys. Chem. Lett., 2014,5(6):1004-1011
46. [46]
  [46] Hayatullah, Murtaza G, Muhammad S, et al. Acta Phys. Pol. A, 2013,124(1):102-107
47. [47]
  [47] Onoda-Yamamuro N, Matsuo T, Suga H. J. Phys. Chem. Solids, 1992,53(7):935-939
48. [48]
  [48] Kulkarni S A, Baikie T, Boix P P, et al. J. Mater. Chem. A, 2014,2(24):9221-9225
49. [49]
  [49] Tanaka K, Takahashi T, Ban T, et al. Solid State Commun., 2003,127(9/10):619-623
50. [50]
  [50] Im J H, Lee C R, Lee J W, et al. Nanoscale, 2011,3(10):4088-4093
51. [51]
  [51] Calabrese J, Jones N L, Harlow R L, et al. J. Am. Chem. Soc., 1991,113(6):2328-2330
52. [52]
  [52] Stranks S D, Eperon G E, Grancini G, et al. Science, 2013,342(6156):341-344
53. [53]
  [53] Colella S, Mosconi E, Fedeli P, et al. Chem. Mater., 2013, 25(22):4613-4618
54. [54]
  [54] Qiu J, Qiu Y, Yan K, et al. Nanoscale, 2013,5(8):3245-3248
55. [55]
  [55] Zhao Y, Zhu K. J. Am. Chem. Soc., 2014,136(35):12241-12244
56. [56]
  [56] Poglitsch A, Weber D. J. Chem. Phys., 1987,87(11):6373-6378
57. [57]
  [57] Noh J H, Im S H, Heo J H, et al. Nano Lett., 2013,13(4):1764-1769
58. [58]
  [58] Edri E, Kirmayer S, Kulbak M, et al. J. Phys. Chem. Lett., 2014,5(3):429-433
59. [59]
  [59] Jiang Q, Rebollar D, Gong J, et al. Angew. Chem. Int. Ed., 2015,127(26):7727-7730
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Modulation of the Structure and Property of ABX3 Type Perovskite Photovoltaic Material

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通讯作者: 陈斌, bchen63@163.com

Modulation of the Structure and Property of ABX₃ Type Perovskite Photovoltaic Material