Citation: LIU Quan, CHEN Qiu-Fang, YU Hong, ZHAO Xin, ZHANG Wen-Hua, LANG Jian-Ping. Two One-Dimensional [MS4Cu4]-Supported Coordination Polymers: Assembly and Crystal Structures of {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo, W; ani=aniline)[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1805-1810. doi: 10.11862/CJIC.2015.237
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Reactions of the preformed cluster precursors [Et4N]4[MS4Cu4I6] (M=Mo (1a); W (1b)) with a ditopic bridging ligand 1, 2-bis(4-pyridyl)ethane (bpe) in aniline solutions gave rise to two analogous one-dimensional cluster-supported coordination polymers {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo (2), W (3); ani=aniline). Both 2 and 3 are characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction. X-ray analyses revealed that the pentanuclear saddle-shaped [MS4Cu4] cores in 1a and 1b are retained in 2 and 3. The adjacent [MS4Cu4] cores are interconnected by double bpe bridges to afford one-dimensional zigzag chains extending along the [111] direction.
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