Citation: WU Jian-Feng, ZHANG Hai-Xia, ZHANG Peng, ZHAO Lang, TANG Jin-Kui. Magnetic Relaxation in 1D and 2D Dysprosium(Ⅲ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1847-1854. doi: 10.11862/CJIC.2015.236 shu

Magnetic Relaxation in 1D and 2D Dysprosium(Ⅲ) Coordination Polymers

1.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: TANG Jin-Kui,
Received Date: 29 May 2015
Available Online: 13 July 2015
Fund Project: 国家自然科学基金(No.21371166)资助项目。 (No.21371166)

Two dysprosium complexes, [Dy₂(OAc)₆H₂O]_n (1) and {[DyL(H₂O)₄]ClO₄·H₂O}_n (2) (L=2, 2'-dithiobis(3-pyridinecarboxylic acid)), were synthesized and structurally and magnetically characterized. Complex 1 is a 1D dysprosium chain, in which the dysprosium ions are bridged by OAc^- anions, exhibiting slow magnetic relaxation behavior with an energy barrier of 2 K. Complex 2 is a 2D dysprosium network, in which the carboxylato-bridged dysprosium chains are linked by disulfide bonds, showing ferromagnetic interaction and slow magnetic relaxation.
- slow magnetic relaxation;ferromagnetic interaction;disulphide bond
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沈阳化工大学材料科学与工程学院沈阳 110142