Citation: DING Fang-Fang, ZHANG Na, ZHANG Jian-Yong, WANG Min, GAO En-Qing. Two Low Dimensional Cd(Ⅱ) Coordination Polymers Constructed from Zwitterionic Dicarboxylate Ligand: Syntheses, Structures, and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 1929-1937. doi: 10.11862/CJIC.2015.231 shu

Two Low Dimensional Cd(Ⅱ) Coordination Polymers Constructed from Zwitterionic Dicarboxylate Ligand: Syntheses, Structures, and Fluorescent Properties

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1 Shanghai Institute of Technology, Shanghai 200235, China;
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2 Science and Technology on Electromagnetic Scattering Laboratory, Shanghai 200438, China;
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3 Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China

Corresponding author: ZHANG Jian-Yong,
Received Date: 27 January 2015
Available Online: 4 June 2015
Fund Project: 上海市自然科学基金(No.14ZR1447900) (No.14ZR1447900)校复合材料学科建设项目(No.10210Q140001)资助。 (No.10210Q140001)

By controllable syntheses, two low dimensional Cd(Ⅱ) complexes with the newly zwitterionic dicarboxylate ligand 1-(4-carboxylatobenzyl)pyridinium-4-carboxylate (HL), {Cd(L)₂·4H₂O}_n(1), and {[Cd(L)(N₃)]·3H₂O}_n(2) have been synthesized and structurally characterized by IR, elemental analyses, single-crystal X-ray diffraction. In compound 1, the eight-coordinated Cd(Ⅱ) ions are chelated by four equivalent L in a bis(chelating) mode, forming a one-dimensional coordination polymer structure. In 2, six-coordinated Cd(Ⅱ) ions are triple bridged by two carboxylate groups and an azide ion into 1D uniform [Cd(N₃)(OCO)₂]_n chains, which are further interlinked through the cationic N-benzylpyridinium backbones of the L ligands into 2D sheet. Interestingly, the fluorescence measurements show that all compounds exhibit intense blue emission in the solid state, and the emission bands are correlated to the coordination modes of the L ligand. CCDC:1031439, HL; 1031440, 1; 1031441, 2.
- zwitterionic ligand;crystal structure;coordination polymers;fluorescence;cadmium(Ⅱ) complex
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