Citation: ZHOU Lian, TIE Sheng-Nian, WANG Zhi-Guo. Syntheses, Crystal Structures and Properties of Coordination Polymers Built from a Semi-rigid Tripod Carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1480-1488. doi: 10.11862/CJIC.2015.221
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By using a semi-rigid multidentate carboxylate linker 3,3',3"-(((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))tribenzoic acid (H3L), four coordination polymers, namely, {[Cd3(L)2(H2O)2]·5DMF·6H2O}n (1), {[Co3(L)2(H2O)2]·2DMF·6H2O}n (2), {[Mn3(L)2(H2O)2]·3DMF·6H2O}n (3), {[Zn3(L)2(H2O)2]·5DMA·5H2O}n (4) were obtained and characterized by single crystal X-ray diffraction, thermogravimetric, elemental analysis, thermal analyses, IR spectra and fluorescence. Four compounds are isostructural with hourglass M3 clusters and L3- ligands as secondary building units (SBUs) to form a pumpkin-shaped metalorganic nanocage, and possess a three-connected node (3,3,6)-connected 3D network. Compounds 1 and 4 exhibited strong photoluminescent emissions at room temperature with a peak at 385 nm, owing to a ligand-centered excited state. The emission intensities of the compound 1 varied upon contact with different solvents or analytes, exhibiting selective emission quenching responses towards nitroaromatics. CCDC: 1041419, 1; 1041420, 2; 1041421, 2; 1041422, 4.
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-
[1]
[1] (a)Eddaoudi M, Moler D B, Li H L, et al. Acc. Chem. Res., 2001,34(4):319-330
-
[2]
(b)Lim D W, Yoon J W, Ryu K Y, et al. Angew. Chem. Int. Ed., 2012,124:9952-9955
-
[3]
[2] (a)Sumida K, Rogow D L, Mason J A, et al. Chem. Rev., 2012, 112:724-781
-
[4]
(b)Wang C, Xie Z G, DeKrafft K E, et al. J. Am. Chem. Soc., 2011,133(34):13445-13454
-
[5]
[3] (a)Kurmoo M. Chem. Soc. Rev., 2009,38:1353-1379
-
[6]
(b)Sato O, Tao J, Zhang Y Z, et al. Angew. Chem. Int. Ed., 2007,46(13):2152-2187
-
[7]
(c)Zhang M, Bosch M, Gentle T, et al. CrystEngComm, 2014, 16:4069-4083
-
[8]
[4] (a)Cui Y, Yue Y, Qian G, et al. Chem. Rev., 2012,112:1126-1162
-
[9]
(b)Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352
-
[10]
[5] KrenoL E, Leong K, Farha O K, et al. Chem. Rev., 2012,112:1105-1125
-
[11]
[6] (a)Tan C R, Yang S H, Champness N R, et al. Chem. Commun., 2011,47:4487-4489
-
[12]
(b)Lin X, Telepeni I, Blake A J, et al. J. Am. Chem. Soc., 2009,131(6):2159-2171
-
[13]
[7] (a)Xue Y S, Jin F Y, Zhou L, et al. Cryst. Growth Des., 2012, 12(12):6158-6164
-
[14]
(b)Zhou L, Zhang J, Li Y Z, et al. CrystEngComm, 2013,15:8989-8997
-
[15]
[8] (a)Zhang J P, Kitagawa S. J. Am. Chem. Soc., 2008,130(3):907-917
-
[16]
(b)Thallapally P K, Tian J, Kishan M R, et al. J. Am. Chem. Soc., 2008,130(50):16842-16843
-
[17]
[9] (a)Qu L L, Zhu Y L, Zhang J, et al. CrystEngComm, 2012,14:824-831
-
[18]
(b)Liang L L, Ren S B, Zhang J, et al. Dalton Trans., 2010, 39:7723-7726
-
[19]
(c)Xue Y S, He Y B, Ren S B, et al. J. Mater. Chem., 2012, 22:10195-10199
-
[20]
[10] (a)Zhang J, Xue Y S, Li Y Z, et al. CrystEngComm, 2012, 14:8215-8221
-
[21]
(b)Zhan C, Zou C, Kong G Q, et al. Cryst. Growth Des., 2013,13(4):1429-1437
-
[22]
(c)Ma C H, Wu Y, Zhang J, et al. CrystEngComm, 2012,14:5166-5169
-
[23]
[11] SMART and SADABS, Bruker AXS Inc., Madison, Wisconsin, USA, 1997.
-
[24]
[12] Sheldrick G M. Acta Cryst., 2008,A64:112-122
-
[25]
[13] (a)Spek A L. J. Appl. Crystallogr., 2003,36:7-13
-
[26]
(b)Spek A L. PLATON, A Multipurpose Crystallographic Tool, Utrecht University, The Netherlands, 2006.
-
[27]
[14] Dai J C, Wu X T, Fu Z Y, et al. Inorg. Chem., 2002,41(6):1391-1396
-
[28]
[15] LIN Zu-Jin(林祖金), LIN Xi(林熙), CAO Rong(曹荣). Acta Chim. Sinica(化学学报), 2012,70:2012-2015
-
[29]
[16] (a)Lakowicz J R. Principles of Fluorescence Spectroscopy. 3rd Ed. Berlin:Springer, 2006.
-
[30]
(b)Valeur B. Molecular Fluorescence:Principles and Application. Weinheim:Wiley-VCH, 2002.
-
[31]
[17] Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352
-
[32]
[18] (a)Lan A, Li K, Wu H, et al. Angew. Chem. Int. Ed., 2009, 48(13):2334-2338
-
[33]
(b)Pramanik S, Zheng C, Zhang X, et al. J. Am. Chem. Soc., 2011,133(12):4153-4155
-
[34]
(c)Guo M, Sun Z M. J. Mater. Chem., 2012,22:15939-15946
-
[35]
(d)Xue Y S, He Y B, Zhou L, et al. J. Mater. Chem. A, 2013, 1:4525-4530
-
[36]
[19] Fang Q, Geng J, Liu B, et al. Chem. Eur. J., 2009,15(43):11507-11514
-
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