Citation: YANG Hong, HAN Xin-Li. Syntheses, Crystal Structures and Cleavage Mechanism of C-S Bond in Cd(Ⅱ) and Zn(Ⅱ) Complexes with Tris(2-mercaptopyridyl) methane[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1597-1602. doi: 10.11862/CJIC.2015.217 shu

Syntheses, Crystal Structures and Cleavage Mechanism of C-S Bond in Cd(Ⅱ) and Zn(Ⅱ) Complexes with Tris(2-mercaptopyridyl) methane

YANG Hong ^1,, ,
HAN Xin-Li ²

1.
1. Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China;
2.
2. Shandong Xinhua Pharmaceutical Co., Ltd., Zibo, Shandong 255086, China

Corresponding author: YANG Hong,
Received Date: 18 September 2014
Available Online: 2 July 2015

Two complexes of Cd(Ⅱ) or Zn(Ⅱ) with L (L=tris(2-mercaptopyridyl)methane), Cd(L)₄(NO₃)₂ (1) and Zn(L)₄(ClO₄)₂ (2), have been synthesized and characterized. The cleavage of the C-S bonds of the ligand has been discovered and the cleavage mechanism has been studied by UV-Vis titration and GC-MS. The possible reaction mechanism has been proposed. Single crystal X-ray analyses show that the Cd and Zn atoms are all in a four-coordinated distorted tetrahedron environment. The intermolecular π-π stacking action extends the complex 1 to a 2D net work. CCDC: 627210, 1; 644051, 2.
- tris(2-mercaptopyridyl)methane;cleavage of the C-S bonds;π-π stacking action
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