Citation: GAO Hong-Ling, BI Yan-Xia, ZHANG Qin-Qin, CUI Jian-Zhong. Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1603-1608. doi: 10.11862/CJIC.2015.215 shu

Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid

1.
Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China

Corresponding author: CUI Jian-Zhong,
Received Date: 19 March 2015
Available Online: 19 May 2015
Fund Project: 国家自然科学基金(No.21271137,21473121) (No.21271137,21473121)教育部先进能源材料化学重点实验室开放基金(南开大学)资助项目。 (南开大学)

Two complexes with pyrazine polycarboxylic acid, namely {[Cu₂(pztc)(4,4'-bpy)(H₂O)₄]·6H₂O}_n (1), {(H₂bpe)[Cd(pztc)(H₂O)₂]·2.5H₂O}_n (2), (H₄pztc=pyrazine-2,3,5,6-tetracarboxylic acid, bpe=1,2-bis(4-pyridyl)ethane, 4,4'-bpy=4,4'-bipyridine), have been prepared by modifying the reaction conditions at room temperature and characterized by IR, elemental analysis, thermal gravimetric analysis, fluorescence measurement and single crystal X-ray diffraction analysis. The structures of two complexes are two-dimensional (2D) networks, but H₄pztc has different connection modes in 1 and 2. Complex 2 shows good luminescence properties in solid state at room temperature. Electron Paramagnetic Resonance (EPR) spectra of complex 1 is studied. CCDC: 1039147, 1; 1039296, 2.
- pyrazine polycarboxylic ligand;two-dimensional network;fluorescent property;electron paramagnetic resonance spectra
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沈阳化工大学材料科学与工程学院沈阳 110142