Citation: ZHONG Wei, YAN Hong. Reactivity of Unsaturated 16e Half-Sandwich Complex Cp*Ir(S2C2B10H10) with ortho- and meta-Substituted Phenyl Azides[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1305-1314. doi: 10.11862/CJIC.2015.205
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To test the influence of the position and electronic effect of the substituted group on the reaction system, detailed studies on the reactivity of unsaturated 16e half-sandwich complex Cp*Ir(S2C2B10H10) (1) with ortho- and meta-substituted phenyl azides were performed. Reaction of 1 with ortho- and meta-substituted phenyl azides led to the formation of metal complexes in which C-H activation at ortho-position of aryl ring happened to construct a new C-S bond. These complexes were fully characterized by NMR (1H, 11B, 13C), FTIR, MS, elemental analysis and single crystal X-ray diffraction. Basing on the results of the same reaction system with irradiation, the radical mechanism for the formation of these complexes was proposed.
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