Citation: ZHONG Wei, YAN Hong. Reactivity of Unsaturated 16e Half-Sandwich Complex Cp^*Ir(S₂C₂B₁₀H₁₀) with ortho- and meta-Substituted Phenyl Azides[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1305-1314. doi: 10.11862/CJIC.2015.205 shu

Reactivity of Unsaturated 16e Half-Sandwich Complex Cp^Ir(S₂C₂B₁₀H₁₀) with ortho- and meta*-Substituted Phenyl Azides

ZHONG Wei ^1,2,, ,
YAN Hong ^2,,

1.
1 College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China;
2.
2 State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: ZHONG Wei, YAN Hong,
Received Date: 2 February 2015
Available Online: 2 June 2015
Fund Project: 国家自然科学基金(No.21301071)资助项目。 (No.21301071)

To test the influence of the position and electronic effect of the substituted group on the reaction system, detailed studies on the reactivity of unsaturated 16e half-sandwich complex Cp^*Ir(S₂C₂B₁₀H₁₀) (1) with ortho- and meta-substituted phenyl azides were performed. Reaction of 1 with ortho- and meta-substituted phenyl azides led to the formation of metal complexes in which C-H activation at ortho-position of aryl ring happened to construct a new C-S bond. These complexes were fully characterized by NMR (1H, 11B, 13C), FTIR, MS, elemental analysis and single crystal X-ray diffraction. Basing on the results of the same reaction system with irradiation, the radical mechanism for the formation of these complexes was proposed.
- half-sandwich complex;substituted phenyl azide;reactivity;mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142

Reactivity of Unsaturated 16e Half-Sandwich Complex Cp*Ir(S2C2B10H10) with ortho- and meta-Substituted Phenyl Azides

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通讯作者: 陈斌, bchen63@163.com

Reactivity of Unsaturated 16e Half-Sandwich Complex Cp^Ir(S₂C₂B₁₀H₁₀) with ortho- and meta*-Substituted Phenyl Azides