Citation: YE Qin, XIANG Jun, LI Jia-Le, LIU Min, XU Jia-Huan, SHEN Xiang-Qian. Fabrication and Microwave Absorption Properties of NZFO-PZT Magnetoelectric Composite Nanofibers[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1296-1304. doi: 10.11862/CJIC.2015.204 shu

Fabrication and Microwave Absorption Properties of NZFO-PZT Magnetoelectric Composite Nanofibers

YE Qin ¹ ,
XIANG Jun ^1,, ,
LI Jia-Le ¹ ,
LIU Min ¹ ,
XU Jia-Huan ^1,, ,
SHEN Xiang-Qian ²

1.
1 School of Mathematics and physics, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China;
2.
2 School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: XIANG Jun, XU Jia-Huan,
Received Date: 14 April 2015
Available Online: 29 May 2015
Fund Project: 国家自然科学基金(No.11204108) (No.11204108)中国博士后科学基金(No.2013M540418) (No.2013M540418)江苏省博士后科研资助计划(No.1301055B)资助项目。 (No.1301055B)

(1-x)Ni_0.5Zn_0.5Fe₂O₄-(x)Pb(Zr_0.52Ti_0.48)O₃ (known simply as (1-x)NZFO-(x)PZT, x=0.1, 0.2, 0.3, 0.4, and 0.5) magnetoelectric composite nanofibers have been successfully fabricated using the electrospinning method. The effects of PZT content on structures, electromagnetic characteristics and microwave absorption properties of the resultant products have been investigated in detail. It is found that all the as-prepared composites nanofibers are composed of both spinel-structured NZFO and perovskite-structured PZT phases. The appropriate incorporation of PZT phase in the composite nanofibers can improve the electromagnetic impedance matching and attenuation characteristics of the corresponding microwave absorbing coatings due to the synergistic effects between magnetic loss of NZFO and dielectric loss of PZT and the enhanced interfacial effects, and consequently boost their microwave absorption performances. The (1-x)NZFO-(x)PZT composite nanofiber/silicone microwave absorbing coatings with x=0.3 and 0.4 exhibit the strongest microwave absorption ability in the low- and high-frequency ranges, respectively. When the coating thickness is between 2.5 and 5.0 mm, the minimum reflection loss (RL) value of the x=0.3 sample is -77.2 dB at 6.1 GHz and the effective absorption bandwidth with RL below -10 dB reaches 11.2 GHz covering the 2.8~12.9 and 16.9~18 GHz frequency ranges. While for x=0.4 sample, an optimal RL value of -37.6 dB is observed at 18 GHz and the effective absorption bandwidth is up to 12.5 GHz ranging from 3.3 to 12.5 and 14.7 to 18 GHz.
- Ni-Zn ferrite;lead zirconate titanate;magnetoelectric composite nanofiber;microwave absorbing performance;synergistic effect
1. [1]
  [1] Xia T, Zhang C, Oyler N A, et al. Adv. Mater., 2013, 25:6905-6910
2. [2]
  [2] CHEN Xue-Guan(陈雪刚), YE Ying(叶瑛), CHEN Ji-Peng (程继鹏). J. Inorg. Mater.(无机材料学报), 2011, 26(5):449-457
3. [3]
  [3] Zhang X F, Guo J J, Qin G W. Appl. Phys. Lett., 2014, 104: 252404
4. [4]
  [4] Xiang J, Li J L, Zhang X H, et al. J. Mater. Chem. A, 2014, 2:16905-16914
5. [5]
  [5] Jiang J J, Li D, Geng D Y, et al. Nanoscale, 2014, 6:3967-3971
6. [6]
  [6] Vinayasree S, Soloman M A, Sunny V, et al. Compos. Sci. Technol., 2013, 82:69-75
7. [7]
  [7] Qiu J, Qiu T T. Carbon, 2015, 81:20-28
8. [8]
  [8] Liu J W, Che R C, Chen H J, et al. Small, 2012, 8:1214-1221
9. [9]
  [9] XIANG Jun(向军), ZHANG Xiong-Hui(张雄辉), YE Qin(叶芹), et al. Chem. J. Chinese Universities(高等学校化学学报), 2014, 35(7):1379-1387
10. [10]
  [10] Ramesh R, Spaldin N A. Nature Mater., 2007, 6:21-29
11. [11]
  [11] Nan C W, Bichurin M I, Dong S X, et al. J. Appl. Phys., 2008, 103:031101
12. [12]
  [12] Ma J, Hu J M, Li Z, et al. Adv. Mater., 2011, 23:1062-1087
13. [13]
  [13] Mandal A, Das C K. J. Electron. Mater., 2013, 42:121-128
14. [14]
  [14] Mandal A, Das C K. J. Appl. Ploym. Sci., 2014, 131:39926
15. [15]
  [15] Liu J R, Itoh M, Terada M, et al. Appl. Phys. Lett., 2007, 91:093101
16. [16]
  [16] Huang X G, Zhang J, Xiao S R, et al. J. Am Ceram. Soc., 2014, 97:1363-1366
17. [17]
  [17] Yang J, Zhang J, Liang C Y, et al. ACS Appl. Mater. Interfaces, 2013, 5:7146-7151
18. [18]
  [18] LIU Gu(刘顾), WANG Liu-Ying(汪刘应), CHEN Jian-Liang (程建良), et al. J. Mater. Eng.(材料工程), 2015, 43(1):104-112
19. [19]
  [19] Wu H, Pan W, Lin D D, et al. J. Adv. Ceram., 2012, 1(1):2-23
20. [20]
  [20] Wang Z L, Liu X J, Lv M F, et al. J. Phys. Chem. C, 2008, 112:15171-15175
21. [21]
  [21] Albuquerque A S, Ardisson J D, Macedo W A A, et al. J. Appl. Phys., 2000, 87:4352-4357
22. [22]
  [22] Yao D S, Ge S H, Zhou X Y, et al. J. Appl. Phys., 2008, 104:013902
23. [23]
  [23] Guan P F, Zhang X F, Guo J J. Appl. Phys. Lett., 2012, 101: 153108
24. [24]
  [24] Qing Y C, Zhou W C, Luo F, et al. J. Magn. Magn. Mater., 2011, 323:600-606
25. [25]
  [25] Shang R X, Zhang Y, Yan L G, et al. J. Phys. D: Appl. Phys., 2014, 47:065001
26. [26]
  [26] Liu X G, Ou Z Q, Geng D Y, et al. Carbon, 2010, 48:891-897
27. [27]
  [27] REN Li(任丽), ZHANG Rong-Fen(张荣芬), LI Zheng(李铮), et al. Electro. Compon. Mater.(电子元件与材料), 2014, 33 (7):23-28
28. [28]
  [28] Cao J, Fu W Y, Yang H B, et al. J. Phys. Chem. B, 2009, 113:4642-4647
29. [29]
  [29] Wang G Q, Ma L X, Chang Y F, et al. Appl. Surf. Sci., 2012, 258:3962-3966
30. [30]
  [30] Kong L B, Li Z W, Liu L, et al. Int. Mater. Rev., 2013, 58: 203-259
31. [31]
  [31] Chu Y Q, Zhang B, Xiang J. Adv. Mater. Res., 2013, 631-632:429-433
32. [32]
  [32] Zhu Y F, Zhang L, Natsuki T, et al. ACS Appl. Mater. Interfaces, 2012, 4:2101-2106
33. [33]
  [33] Sun G B, Dong B X, Cao M H, et al. Chem. Mater., 2011, 23:1587-1593
34. [34]
  [34] Meng X G, Wan Y Z, Li Q Y, et al. Appl. Surf. Sci., 2011, 257:10808-10814
35. [35]
  [35] Ma Z, Cao C T, Liu Q F, et al. Chin. Phys. Lett., 2012, 29: 038401
1. [1]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
2. [2]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Accelerating the reconstruction of NiSe₂ by Co/Mn/Mo doping for enhanced urea electrolysis. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-0. doi: 10.1016/j.actphy.2025.100083
3. [3]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
4. [4]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
5. [5]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
6. [6]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
7. [7]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
8. [8]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
9. [9]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
10. [10]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
11. [11]
  Ximeng CHI , Jianwei WEI , Yunyun WANG , Wenxin DENG , Jiayi DAI , Xu ZHOU . First-principles study of the electronic structure and optical properties of Au and I doped-inorganic lead-free double perovskite Cs₂NaBiCl₆. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1371-1379. doi: 10.11862/CJIC.20240401
12. [12]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378
13. [13]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
14. [14]
  Ying Liang , Yuheng Deng , Shilv Yu , Jiahao Cheng , Jiawei Song , Jun Yao , Yichen Yang , Wanlei Zhang , Wenjing Zhou , Xin Zhang , Wenjian Shen , Guijie Liang , Bin Li , Yong Peng , Run Hu , Wangnan Li . Machine learning-guided antireflection coatings architectures and interface modification for synergistically optimizing efficient and stable perovskite solar cells. Acta Physico-Chimica Sinica, 2025, 41(9): 100098-0. doi: 10.1016/j.actphy.2025.100098
15. [15]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
16. [16]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
17. [17]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
18. [18]
  Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
19. [19]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . 高效靶向示踪钙钛矿纳米系统光电增效抗肿瘤. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-. doi: 10.1016/j.actphy.2024.100042
20. [20]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(328)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142