Citation: YIN Wei-Dong, LI Gui-Lian, LIU Guang-Zhen, XIN Ling-Yun, LI Xiao-Ling, MA Lu-Fang. Syntheses, Structures and Properties of Two Coordination Polymers Constructed by 3-Nitrobenzene-1,2-dicarboxylate Acid and Zn/Co[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1439-1446. doi: 10.11862/CJIC.2015.202 shu

Syntheses, Structures and Properties of Two Coordination Polymers Constructed by 3-Nitrobenzene-1,2-dicarboxylate Acid and Zn/Co

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471022, China

Corresponding author: LIU Guang-Zhen,
Received Date: 29 March 2015
Available Online: 8 June 2015
Fund Project: 国家自然科学基金(No.20971064, 21271098) (No.20971064, 21271098) 河南省大学科技创新人才(No.14HASTIT017) (No.14HASTIT017) 河南省大学科技创新团队(No.14IRTSTHN008) 资助项目。 (No.14IRTSTHN008)

Two coordination polymers {[Zn(3-Nbdc)(bpmp)]·H₂O}_n (1) and {[Co(3-Nbdc)(bpmp)(H₂O)]·H₂O}_n (2) (3-Nbdc^2-=3-nitrobenzene-1,2-dicarboxylate, bpmp=1,4-bis(4-pyridylmethyl)piperazine) were synthesized hydrother-mally and characterized structurally by single-crystal X-ray diffractions, elemental analysis and infrared spectros-copy (IR). Both complexes 1 and 2 display (4,4) grid layers containing the dinuclear units in 1 and helix metal-carboxylate chains in 2. Thermogravimetric Analyses (TGA), powder X-ray diffractions (PXRD), fluorescence property and magnetic property for compounds 1 and 2 are also investigated. The solid state fluorescence indicates that the complex 1 shows similar emission spectra to the free 3-NbdcH₂ ligand due to little contribution from the Zn-O inorganic motifs to the emission and very little degree change of interligand coupling upon metal coordination. The complex 2 exhibits a ferromagnetic coupling between the metal centers in the low-temperature region, and the decrease of χ_MT value in the high-temperature region may be attributed to the strong spin-orbit coupling through the ⁴T_1g state of the octahedral Co²⁺ centers.
- hydrothermal synthesis;cobalt;photoluminescence;magnetic property;coordination polymer
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