Citation: ZHANG Qi-Long, CHEN Ming-Hua, RAN Xia, HU Peng. Syntheses and Crystal Structures of Co(Ⅱ), Cu(Ⅱ) Complexes with Phenanthroline Substituted Glycoluril[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1387-1392. doi: 10.11862/CJIC.2015.201 shu

Syntheses and Crystal Structures of Co(Ⅱ), Cu(Ⅱ) Complexes with Phenanthroline Substituted Glycoluril

1.
1 Department of Chemistry, Guizhou Medical University, Guiyang 550004, China;
2.
2 Department of Chemistry & Biology, Xingyi Normal University for Nationalities, Xingyi, Guizhou 562400, China

Corresponding author: ZHANG Qi-Long,
Received Date: 13 April 2015
Available Online: 8 June 2015
Fund Project: 国家自然科学基金(No.21061003) (No.21061003) 贵州省科技厅-贵阳医学院联合基金(黔科合LH字[2014]7090) (黔科合LH字[2014]7090)

Two complexes, {[Co(L)(H₂O)₃]Cl₂·2H₂O}_n(1) and [Cu₂(L)₂Cl₄]·3C₂H₅OH (2) were synthesized from the reaction of phenanthroline substituted glycoluril (L) with CoCl₂·6H₂O and CuCl₂·2H₂O, and characterized by elemental analysis, IR and single crystal X-ray diffraction. Complex 1 crystallized in the orthorhombic system, space group P2₁2₁2₁, the coordination environment of Co(Ⅱ) adopted a distorted octahedron geometry, being bound to three oxygen donor from one H₂O molecule as well as to two nitrogen atoms and oxygen atoms from two adjacent molecules of L. Each ligand L acted as a tridentate ligand coordinating two metal atoms to generate a one-dimensional(1D) chain structure. Complex 2 crystallized in the monoclinic system, space group P2₁/_n, the coordination environment of Cu(Ⅱ) adopted a distorted square taper geometry, being bound to three chlorine atom as well as to two nitrogen atoms from ligand L. There are two chlorine atoms coordinating two metal atoms to generate binuclear complex 2.
- phenanthroline substituted glycoluril;Co(Ⅱ) complex;Cu(Ⅱ) complex;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142