Citation: BAI Shu-Ming, TIAN Jian-Hua, MA Huan-Mei, ZHU Kun-Lei, SHAN Zhong-Qiang. Preparation and Photoelectric Performance of Mn-Doped-CdSSe2 Quantum Dots Sensitized Electrode[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1365-1372. doi: 10.11862/CJIC.2015.197
-
Sodium sulfide-selenium prepared by adding Se powder into the Na2S methanol-water solution was used as the anionic precursor, and the methanol-water solution of Cd(NO3)2 and Mn(CH3COO)2 was used as the cationic precursor, respectively. Then, cadmium sulfide-selenium quantum dots sensitized TiO2 photoanodes (CdSSe2/TiO2) and Mn2+ doped cadmium sulfide-selenium quantum dots sensitized TiO2 photoanodes (Mn-CdSSe2/TiO2) were successfully prepared by the successive ionic layer adsorption and reaction (SILAR) for Quantum dots solar cell (QDSC). The Raman spectrum, XPS were applied to analyze the chemical bonds of the Na2SSe2 precursors. EDX and UV-Vis were investigated the composition and light absorption property of Mn-CdSSe2/TiO2 photoanode. J-V curves and IPCE were used to characterize photovoltaic performance of the as-prepared CdS/TiO2, CdSSe2/TiO2 and Mn-CdSSe2/TiO2 photoanodes. The results reveals that the Mn-CdSSe2/TiO2 photoanode with enhanced energy conversion efficiency has been fabricated by SILAR method using the anionic precursors prepared with 0.12 mol·L-1 Se and 0.5 mol·L-1 Na2S, the cationic precursor of 0.5 mol·L-1 Cd2+ and 0.3 mol·L-1 Mn2+. Compared with the CdSSe2/TiO2 and CdS/TiO2 photoanodes, the efficiency of the Mn-CdSSe2/TiO2 photoanode is increased by 90% and 247%, separately.
-
-
[1]
[1] HAN ZhiZhong(韩志钟), WEI Li-Yuan(韦力瑗), GUO Ye (郭晔), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29(9):1856-1862
-
[2]
[2] Nozik A J. Physica E, 2002, 14(1):115-120
-
[3]
[3] CHENG Kan(成戡), FANG Zheng(方正), MA Yun-Fei (马云飞), et al. Chinese J. Inorg. Chem. (无机化学学报), 2013, 29(2):326-332
-
[4]
[4] Lee W, Kwak W C, Min S K, et al. Electrochem. Commun., 2008, 10(11):1699-1702
-
[5]
[5] Huang Z, Zou X, Zhou H. Mater. Lett., 2013, 95:139-141
-
[6]
[6] Lee J W, Son D Y, Ahn T K, et al. Sci. Rep., 2013, 3
-
[7]
[7] Santra P K, Kamat P V. J. Am. Chem. Soc., 2012, 134(5): 2508-2511
-
[8]
[8] Lee Y L, Chang C H. J. Power Sources, 2008, 185(1):584-588
-
[9]
[9] Haase V, Kirschstein G, Rieger H, et al. Gemlin Handbook of Inorganic Chemistry, Selen, Suppl A3. NewYork: Springer Berlin Heidelberg. 1981:318-319
-
[10]
[10] Machado K D, Dubiel A S, Deflon E, et al. Solid State Commun., 2010, 150(29): 1359-1363
-
[11]
[11] Fan H M, Ni Z H, Feng Y P, et al. Appl. Phys. Lett., 2007, 91(17):171911
-
[12]
[12] Pashutski A, Folman M. Surf. Sci., 1989, 216(3):395-408
-
[13]
[13] Palchan I, Crespin M, Estrade-Szwarckopf H, et al. Chem. Phys. Lett., 1989, 157(4):321-327
-
[14]
[14] Shul'ga Y M, Rubtsov V I, Vasilets V N, et al. Synth. Met., 1995, 70(1):1381-1382
-
[15]
[15] Tkachenko O P, Shpiro E S, Wark M, et al. J. Chem. Soc., Faraday Trans., 1993, 89(21):3987-3994
-
[16]
[16] Kumar S, Kashyap S C, Chopra K L. J. Appl. Phys., 1992, 72(5):2066~2068
-
[17]
[17] Salitra G, Hodes G, Klein E, et al. Thin Solid Films, 1994, 245(1):180-185
-
[18]
[18] Bahl M K, Watson R L, Irgolic K J. J Chem Phys, 1980, 72 (7):4069-4077
-
[19]
[19] Gaarenstroom S W, Winograd N J. Chem. Phys., 1977, 67 (8):3500-3506
-
[20]
[20] Shu T, Zhou Z, Wang H, et al. J. Mater. Chem., 2012, 22 (21):10525-10529
-
[21]
[21] Chen H, Zhu L, Liu H, et al. J. Power Sources, 2014, 245: 406-410
-
[22]
[22] Raj C J, Karthick S N, Park S, et al. J. Power Sources, 2014, 248:439-446
-
[1]
-
-
[1]
Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO4 photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
-
[2]
Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
-
[3]
Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
-
[4]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[5]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[6]
Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
-
[7]
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
-
[8]
Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
-
[9]
Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
-
[10]
Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
-
[11]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[12]
Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
-
[13]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[14]
Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
-
[15]
Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
-
[16]
Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
-
[17]
Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
-
[18]
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
-
[19]
Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
-
[20]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[1]
Metrics
- PDF Downloads(1)
- Abstract views(412)
- HTML views(98)