Citation: YANG Zai-Wen, DING Zuo-Cheng, LIU Xiang-Rong, ZHAO Shun-Sheng, ZHANG Run-Lan, YANG Shui-Lan. Crystal Structures and Thermochemical Properties of Phenyl-acetic Acid Furan-2-ylmethylene-hydrazide and Its Ni(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1520-1528. doi: 10.11862/CJIC.2015.196 shu

Crystal Structures and Thermochemical Properties of Phenyl-acetic Acid Furan-2-ylmethylene-hydrazide and Its Ni(Ⅱ) Complex

1.
College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China

Corresponding author: LIU Xiang-Rong,
Received Date: 25 December 2014
Available Online: 10 May 2015
Fund Project: 国家自然科学基金项目(No.21373158,21301139,21103135) (No.21373158,21301139,21103135)陕西省教育厅科研计划项目(No.2013JK0651)资助。 (No.2013JK0651)

The Phenyl-acetic acid furan-2-ylmethylene-hydrazide (H₂L: C₁₃H₁₂N₂O₂) was synthesized from methyl phenylacetate, hydrazine hydrate and furfural, and then reacted with nickel chloride hexahydrate to form a complex Ni(HL)₂ (1). The structures of H₂L and 1 were determined by X-ray single crystal diffraction and element analysis.The X-ray single crystal diffraction showed that the crystal of H₂L belonged to monoclinic system, space group P2₁/c with a=1.161 9(3) nm, b=1.359 8(3) nm, c=0.792 16(19) nm, β=109.307(4)° and the crystal of the complex 1 belonged to triclinic system, space group P1 with a=0.455 70(14) nm, b=1.094 7(3) nm, c=1.204 8(4) nm, β=98.302(5)°. Thermal gravity analyses were used to investigate the thermal stabilities of H₂L and 1, and the apparent activation energy (E_a) of the decompositions were also calculated, and the results indicated that the complex 1 was more thermal stable than the ligand H₂L. The microcalorimetric method was used to study the interactions of H₂L and the complex 1 with calf thymus DNA (CT-DNA), and the experimental results showed that the enthalpy change (ΔH) of the complex 1 was greater than that of the ligand H₂L, indicating that the complex 1 displayed stronger interaction with CT-DNA than the ligand H₂L. CCDC: 909434, H₂L; 949203, 1.
- acylhydrazone;Ni(Ⅱ) complex;crystal structure;thermal stability;microcalorimetry
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沈阳化工大学材料科学与工程学院沈阳 110142