Citation: WANG Ying, XUE Bing, LI Yi-Lin, LI Si-Nan, XU Chong-Fu. Extensive Hydrosilation of Acetyl Manganese Pentacarbonyl[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1393-1401. doi: 10.11862/CJIC.2015.194 shu

Extensive Hydrosilation of Acetyl Manganese Pentacarbonyl

WANG Ying ^1,2 ,
XUE Bing ¹ ,
LI Yi-Lin ¹ ,
LI Si-Nan ¹ ,
XU Chong-Fu ^1,2,,

1.
1 College of Petrochemical Engineering of Changzhou University, Changzhou, Jiangsu 213164, China;
2.
2 Jiangsu Province Key Laboratory of Green Catalytic Materials and Technologies Changzhou, Jiangsu 213164, China

Corresponding author: XU Chong-Fu,
Received Date: 23 March 2015
Available Online: 22 May 2015
Fund Project: 国家自然科学基金(No.21376032)资助项目。 (No.21376032)

(CO)₅MnCOCH₃ (1) was synthesized in two steps. A solution 1 with Me₂PhSiH in C₆D₆ was continuously monitored by ¹H NMR spectroscopy for 9 h and reaction profile was established using timely contents (mmol) obtained by directly integrating chemical labels of the reactants and derivatives against that of the internal standard C₆H₅(CH₂)₂C₆H₅. 9 intermediates and final products emerged in the extensive hydrosilation were prepared and the molecular structures of the derivations generated in the reaction process were positively confirmed by comparison of their NMR spectra with that of real substances. All besides the 6 species that were quantified by direct integration of their chemical labels the other 3 were indirectly quantified by combination of chemical stoichiometry and integration of their chemical labels. Attempt was made to make plausible explanations for the origins of these species. Finally, a mechanism with multiple step reactions process and double pathways was proposed. More than 90.7% of the total manganese source was accounted for at 9 h and meanwhile that of more than 91.4% of the total silicon source was accounted for.
- hydrosilation;integrating chemical labels;multiple step process;double pathways mechanism
1. [1]
  [1] Gregg B T, Hanna P K, Crawford E J, et al. J. Am. Chem. Soc., 1991, 113(47):384-385
2. [2]
  [2] Hanna P K, Gregg B T, CutlerA R. Organometallics, 1991, 10(1):31-33
3. [3]
  [3] Ziegler T, Verslius L, Tschinke V J. J. Am. Chem. Soc., 1986, 108(21):612-614
4. [4]
  [4] Axe F U, Marynick D S. Organometallics, 1987, 6(17):572-575
5. [5]
  [5] Wegman R W. Organometallics, 1986, 5(3):707-710
6. [6]
  [6] Kovacs I, Sisak A, Ungvary F, et al. Organometallics, 1988, 7 (10):1025-1029
7. [7]
  [7] Glaysz J A. Acc. Chem. Res., 1984, 17(57):326-330
8. [8]
  [8] Selover J C, Vaughn G D, Strouse C E, et al. J. Am. Chem. Soc., 1986, 108(11):1455-1457
9. [9]
  [9] Vaughn G D, Glaysz J A. J. Am. Chem. Soc., 1986, 108(35): 1473-1475
10. [10]
  [10] Gregg B T, Cutler A R. J. Am. Chem. Soc., 1996, 118, 42 (19):10069-10084
11. [11]
  [11] Krein K A, Gladysz J A. Organometallics, 1986, 5(15):936-940
12. [12]
  [12] Mars M, Brinkman K C, Lisensky C A, et al. J. Org. Chem., 1985, 50(24):3396-3398
13. [13]
  [13] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), CHEN Miao(陈苗), et al. Acta Chim. Sin.(化学学报), 2008, 66(10): 1239-1244
14. [14]
  [14] Gregg B T, Cutler A R. Organometallics, 1994, 13(9):1039-1043
15. [15]
  [15] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), XUE Bing (薛冰), et al. Acta Chim. Sin.(化学学报), 2011, 69(8):999-1006
16. [16]
  [16] Gladysz J A, Williams G M, Tam W, et al. Inorg. Chem., 1979, 18(3):553-558
17. [17]
  [17] Warner K E, Norton J R. Organometallics, 1985, 4(16):2150-2154
18. [18]
  [18] Tan K Y D, Teng G F, Fan W Y. Organometallics, 2011, 30 (15):4136-4143
19. [19]
  [19] Anderson G K. Acc. Chem. Res., 1984, 17(21):67-74
20. [20]
  [20] Gregg B T, Cutler A R. Organometallics, 1998, 17(32):4169-4175
21. [21]
  [21] Gray L M, Donald A T. Inorganic Chemistry. New Jersey: Prentice Hall, 1999:297
22. [22]
  [22] Gregg B T, Cutler A R. J. Am. Chem. Soc., 1995, 117(10): 10139-10140
23. [23]
  [23] Mao Z, Gregg B T, Cutler A R. Organometallics, 1998, 17(10): 1993-2002
24. [24]
  [24] Green M L H, Nagy P L I. J. Organomet. Chem., 1963, 1(27): 58-60
25. [25]
  [25] Xu C F, Anderson G K A. Organometallics, 1996, 15(7):1760-1764
26. [26]
  [26] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), XUE Bing (薛冰), et al. Acta Chim. Sin.(化学学报), 2009, 67(20):2355-2362
27. [27]
  [27] LI Rong (厉荣), CHEN Peng-Gang(陈鹏刚). Chinese J. Inorg. Chem.(无机化学学报), 2008, 24(20):657-660
1. [1]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
5. [5]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
6. [6]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
7. [7]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
8. [8]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
9. [9]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
10. [10]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
11. [11]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
12. [12]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
13. [13]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
14. [14]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
15. [15]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
16. [16]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(312)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142