Citation: ZHAI Chang-Wei, CHENG Mei-Ling, HAN Wei, LIU Qi. Syntheses, Crystal Structures and Luminescent Properties of Manganese and Cadmium Complexes Based on 5-Methyl-1H-Pyrazole-3-Carboxylic Acid and Phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1409-1416. doi: 10.11862/CJIC.2015.193
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One monomeric complex [Mn(HMPCA)2(phen)]·2H2O (1) and one 1D coordination polymer [Cd2(HMPCA)2 (phen)2(H2O)2]·2H2O (2) with binuclear structural unit (H2MPCa=5-methyl-1H-pyrazole-3-carboxylic acid, phen=phenanthroline) have been synthesized and characterized by elemental analysis, IR spectra, thermogravimetric analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic system, space group P1, while 2 in the orthorhombic system, space group Pccn. In 1, Mn(Ⅱ) ion located in a distorted octahedral coordination geometry, discrete water molecules and mononucleate units are assembled into a 3D supramolecular network. In 2, each Cd(Ⅱ) ion located in a pentagonal bipyramid geometry. Each carboxyl group from HMPA- anion bridges two adjacent Cd(Ⅱ) ions, forming a 1D chain. These chains and water molecules are connected by hydrogen bonds, forming a 3D supramolecular framework. The thermal stability and luminescent properties of them are also investigated. CCDC: 1044243, 1; 1044244, 2.
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