Citation: ZHANG Lu, ZENG Su-Yuan, LIU Tao, SUN Jun-Shan, DOU Jian-Min, JIANG Jian-Zhuang. Mixed Tetrapyrrole Terbium Triple-Decker Single Molecule Magnets with Bulky Inorganic Polyhedral Oligomeric Silsesquioxanes Moieties at Outer Porphyrin Peripheries[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1761-1773. doi: 10.11862/CJIC.2015.190 shu

Mixed Tetrapyrrole Terbium Triple-Decker Single Molecule Magnets with Bulky Inorganic Polyhedral Oligomeric Silsesquioxanes Moieties at Outer Porphyrin Peripheries

1.
1. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China;
2.
2. Department of Chemistry, Liaocheng University, Liaocheng, 252004, China;
3.
3. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116012, China

Corresponding author: DOU Jian-Min, JIANG Jian-Zhuang,
Received Date: 1 April 2015
Available Online: 22 May 2015
Fund Project: 国家自然科学基金(No.21290174) (No.21290174)国家重点基础研究发展计划(973计划)(No.2013CB933402和No.2012CB224801)。 (973计划)(No.2013CB933402和No.2012CB224801)

Bulky inorganic polyhedral oligomeric silsesquioxanes (POSS) moieties were introduced onto the porphyrin periphery in mixed (phthalocyaninato) (porphyrinato) terbium molecule, giving POSS-involved hybrid triple-decker complex Tb₂(Pc)[T(OPOSS)₄PP]₂ (1) [H₂Pc=phthalocyanine; H₂T(OPOSS)₄PP=5, 10, 15, 20-tetra{[[N-[heptakis(isobutyl)propoxy]phenyl]octasiloxane]}porphyrin]. For comparative study, triple-decker analogue Tb₂(Pc)(TPP)₂ (2) (H₂TPP=5, 10, 15, 20-tetraphenyporphyrin) was also prepared and structurally characterized. In particular, Tb₂(Pc)[T(OPOSS)₄PP]₂ (1) and Tb₂(Pc)(TPP)₂ (2) were revealed to display intrinsic single molecule magnet (SMM) and non-SMM (or field-induced) characteristic, respectively, at zero Oe (or a 3.0 Oe ac field), clearly indicating the effect of the covalently linked, homogenously dispersed POSS moieties on effectively separating the magnetic cores and improving the magnetic property of triple-decker compounds.
- tetrapyrrole;sandwich POSS;molecular hybrid;single molecule magnet
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