Citation: HU Jia-Hua, DENG Wei, JIANG Xuan-Feng, YU Shu-Yan. Tuning Supramolecular Chiral Architecture of Molecular Corners from Achiral Dipalladium(Ⅱ) and Diplatinum(Ⅱ) Complexes with Achiral Anthracyl Pyrazole Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1278-1286. doi: 10.11862/CJIC.2015.185
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A novel kind of coordination molecular corners [M2L2] ([1=(bpy)Pd]2L2, 2=[(dmbpy)Pd]2L2, 3=[(phen)Pd]2L2, 4=[(ppy)Pt]2L2, where bpy=2,2'-bipyridine, dmbpy=4,4'-dimethyl-2,2'-bipyridine, phen=1,10-phenanthroline, ppy=2-phenylpyridine) was synthesized through synergistic metal-metal bonding interaction and spontaneous deprotonation from the pyrazole linkers 4-(4-(anthracen-9-yl)phenyl)-3,5-dimethyl-1H-pyrazole (L). Three complexes 1~3 were characterized by single crystal X-ray diffraction, 1H and 13C NMR, ESI-MS and fluorescence spectroscopy. The neutral organometallic corner [(ppy)Pt]2L2 4 was also determined by 1H and 13C NMR, MALDI-TOF-MS and fluorescence spectroscopy. These achiral molecular corners assemble from different achiral dimetallic centers with the achiral ligand HL in quite different crystal structures, in particular, 3 with a [(phen)Pd]2 assembling center crystallizes into a supramolecular chiral architecture.
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-
[1]
[1] Sauvage J P. Transition Metals in Supramolecular Chemistry, Perspectives in Supramolecular Chemistry: Vol.5. New York: Wiley, 1999.
-
[2]
[2] Fujita M. Molecular Self-Assembly Organic Versus Inorganic Approach (Structure and Bonding): Vol.96. New York: Springer, 2000.
-
[3]
[3] Caulder D L, Raymond K N. Acc. Chem. Res., 1999, 32:975-982
-
[4]
[4] Navarro J A R, Lippert B. Coord. Chem. Rev., 1999, 185-186:653-667
-
[5]
[5] Fujita M, Tominaga M, Hori A, et al. Acc. Chem. Res., 2005, 38:371-380
-
[6]
[6] Würthner F, You C C, Saha-Möller C R. Chem. Soc. Rev., 2004, 33:133-146
-
[7]
[7] Seidel S R, Stang P J. Acc. Chem. Res., 2002, 35:972-983
-
[8]
[8] Kauffman G B. A Century of Progress, American Chemical Society: Vol.565. Washington DC: Coordination Chemistry, 1994.
-
[9]
[9] Lehn J M. Supramolecular Chemistry, Concepts and Perspe-ctives, Weinheim: VCH, 1995.
-
[10]
[10] Ballhausen C J. Introduction to Ligand Field Theory. New York: McGraw Hill, 1962.
-
[11]
[11] Atwood J D, Wovkulich M J, Sonnenberger D C. Acc. Chem. Res., 1983, 16:350-55
-
[12]
[12] Cotton F A, Walton R A. Multiple Bonds Between Metal Atoms, Oxford: Oxford University Press, 1993.
-
[13]
[13] Cotton F A, Murillo C A, Walton R A. Multiple Bonds Between Metal Atoms: 3rd Ed. New York: Springer Science and Business Media, Inc., 2005.
-
[14]
[14] Cotton F A, Lin C, Murillo C A. Acc. Chem. Res., 2001, 34: 759-771
-
[15]
[15] Chifotides H, Dunbar K R. Acc. Chem. Res., 2005, 38:146-156
-
[16]
[16] Fujita M, Yazaki J , Ogura K. J. Am. Chem. Soc., 1990, 112: 5645-5646
-
[17]
[17] Fujita M, Ogura K. Coord. Chem. Rev., 1996, 148:249-264
-
[18]
[18] Fujita M. Chem. Soc. Rev., 1998, 27:417-426
-
[19]
[19] Fujita M, Umemoto K, Yoshizawa M, et al. Chem. Commun., 2001:509-518
-
[20]
[20] Fujita M, Tominaga M, Hori A, et al. Acc. Chem. Res., 2005, 38:371-380
-
[21]
[21] Alvarez-Vergara M C, Casado M A, Martin M L, et al. Organometallics, 2005, 24:5929-5935
-
[22]
[22] Baudron S A, Hosseini M W. Chem. Commun., 2008:4558-4563
-
[23]
[23] Hiraoka S, Sakata Y, Shionoya M J. Am. Chem. Soc., 2008, 130:10058-10063
-
[24]
[24] Schmittel M, Mahata K. Chem. Commun., 2008:2550-2554
-
[25]
[25] Huang H P, Li S H, Yu S Y, et al. Inorg. Chem. Commun., 2005, 8:656-660
-
[26]
[26] Ning G H, Yao L Y, Liu L X, et al. Inorg. Chem., 2010, 49: 7783-7792
-
[27]
[27] Qin L, Yao L Y, Yu S Y. Inorg. Chem., 2012, 51:2443-2453
-
[28]
[28] Yu S Y, Fujita M, Yamaguchi K. Dalton Trans., 2001:3145-3146
-
[29]
[29] Boixassa A, Pons J, Solans X, et al. Inorg. Chem. Commun., 2003, 6:922-925
-
[30]
[30] Yao L Y, Yu Z S, Qin L, et al. Dalton Trans., 2013:3447-3454
-
[31]
[31] Yu S Y, Jiao Q, Li S H, et al. Org. Lett., 2007, 9:1379-1382
-
[32]
[32] Zhang Z X, Huang H P, Yu S Y, et al. Inorg. Chem., 2004, 20:849-857
-
[33]
[33] Yu S Y, Huang H P, Li S H, et al. Inorg. Chem., 2005, 44: 9471-9488
-
[34]
[34] Conrad R C, Rund J V. Inorg. Chem., 1972, 11:129-134
-
[35]
[35] Yu S Y, Fujita M, Yamaguchi K. Dalton Trans., 2001:3145-3146
-
[36]
[36] Sheldrick G M. SHELXS-97, University of Göttingen, 1990.
-
[37]
[37] Sheldrick G M. SHELXL-97 , University of Göttingen, 1997.
-
[38]
[38] CAChe 6.1.1 for Windows, Fujitsu Ltd., Chiba, Japan, 2003.
-
[39]
[39] Tong J, Yu S Y, Li H. Chem. Commun., 2012, 48:343-5345
-
[40]
[40] Li S H, Huang H P, Yu S Y, et al. Chinese J. Chem., 2006, 24:1225-1229
-
[41]
[41] Sun Q F, Wong K M C, Liu L X, et al. Inorg. Chem., 2008, 47:2142-2154
-
[42]
[42] Ezuhar T, Endo K, Aoyama Y. J. Am. Chem. Soc., 1999, 121:3279-3283
-
[43]
[43] Pons J, Chadghan A, Casabó J, et al. Inorg. Chem. Commun., 2000, 3:296-299
-
[44]
[44] Sakai K, Sato T, Tsubomura T, et al. Cryst. Struct. Commun. Sect. C, 1996, 52:783-786
-
[45]
[45] Li S H, Huang H P, Yu S Y, et al. Dalton Trans., 2005: 2346-2348
-
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