Citation: LI Hai-Qing, HUA Jing-Kun, ZHA Li-Qin, MA Yun-Sheng, TANG Xiao-Yan, XIE Ji-Min, YUAN Rong-Xin. Syntheses, Structures and Magnetic Properties of Two Copper Phosphonates Based on 6-Hydroxy-2-pyridinephosphonic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1417-1424. doi: 10.11862/CJIC.2015.184 shu

Syntheses, Structures and Magnetic Properties of Two Copper Phosphonates Based on 6-Hydroxy-2-pyridinephosphonic Acid

1.
1 School of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, Jiangsu 215500, China;
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2 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: MA Yun-Sheng, YUAN Rong-Xin,
Received Date: 3 February 2015
Available Online: 7 May 2015
Fund Project: 江苏省高校自然科学重大项目(No.12KJA150001,14KJA150001) (No.12KJA150001,14KJA150001) 江苏省科技基础研究计划(No.BK2012643) (No.BK2012643)

Two copper phosphonates [Cu₃(L)₂(bpy)₂(H₂O)₂]·2H₂O (1) and [Cu₃(L)₂(bpy)₂(H₂O)₃]·2H₂O (2) (H₃L=6-hydroxy-2-pyridinephosphonic acid, bpy=4,4'-bipyridine, bpe=trans-1,2-bis(4-pyridyl)ethylene) were synthesized under hydrothermal conditions. In compound 1 the Cu²⁺ ions are bridged by the phosphonate ligand into one chain, which are further bridged by bpy into a 2D layer. The layers are interlinked by hydrogen bonds into 3D supramolecular network. Compound 2 is isostructural to compound 1, however, the bridge ligand is bpe. Magnetic measurements indicate antiferromagnetic interactions are propagated among the Cu²⁺ centers in compound 1 and 2.
- copper compound;phosphonic acid;crystal structure;magnetic properties
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