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Citation: ZHU Xiao-Ming, KUANG Dai-Zhi, FENG Yong-Lan, ZHANG Fu-Xing, YU Jiang-Xi, JIANG Wu-Jiu, ZHANG Zhi-Jian. Syntheses, Crystal Structures, Thermal Stability and Biological Activities of Two Bis[tri(2-methyl-2-phenyl)propyltin]dicarboxylates (CH2)n[CO2Sn(CH2CMe2Ph)3]2 (n=5,6)[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1373-1379. doi: 10.11862/CJIC.2015.181 shu

Syntheses, Crystal Structures, Thermal Stability and Biological Activities of Two Bis[tri(2-methyl-2-phenyl)propyltin]dicarboxylates (CH2)n[CO2Sn(CH2CMe2Ph)3]2 (n=5,6)

  • 1.

    1 Department of Chemistry and Material Science, Hengyang Normal University; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China;

  • 2.

    2 Department of Lifes Science, Hengyang Normal University, Hengyang, Hunan 421008, China

  • Corresponding author: KUANG Dai-Zhi, 
  • Received Date: 8 March 2015
    Available Online: 4 May 2015

    Fund Project: 湖南省自然科学基金(No.13JJ3112) (No.13JJ3112)科技计划(No.2013TZ2025, 2014NK3086, 2014FJ3060) (No.2013TZ2025, 2014NK3086, 2014FJ3060) 功能金属有机材料湖南省普通高校重点实验 室开放基金(No.13K105, 14K014, 13K01-05, GN14K01) (No.13K105, 14K014, 13K01-05, GN14K01) 衡阳师范学院科学基金(No.12C45) (No.12C45)

  • The two bis[tri(2-methyl-2-phenyl)propyltin]dicarboxylates (CH2)n[CO2Sn(CH2CMe2Ph)3]2 (n=5 (1), 6 (2)) have been synthesized by the reaction of pimelic acid and suberic acid with bis[tri(2-methyl-2-phenyl)propyltin]oxide, respectively. IR, 1H and 13C NMR, elemental analysis and X-ray diffraction for the title complexes were presented. The two complexes belong to monoclinic, space group P21/c. The tin atoms have a distorted tetrahedral geometry. A 1D chain structure of complex 1 is generated by intermolecular hydrogen bonds and a 2D network structure of complex 2 is formed by C-H…O and C-H…π interactions. The thermal gravimetric analysis has showed that the complexes 1 and 2 are stable below 340 ℃. The two complexes showed strong in vitro anti-tumor activity against five human tumor cell lines, Colo205, HepG2, MCF-7, Hela and NCI-H460, and have antibacterial activity.
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