Citation: ZHENG Hui, XU Yang, DUAN Chun-Ying. Tuning Intrachain Magnetic Interactions of Cyanide-bridged FeⅢMnⅡ Chain[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1460-1466. doi: 10.11862/CJIC.2015.177
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Two cyanide bridged FeⅢMnⅡ double zigzag chains {[Fe(Tp)(CN)3]2[Mn(bib)]}·CH3OH·2H2O (1) and {[Fe(pzTp)(CN)3]2[Mn(bib)]}·3H2O (2) were synthesized utilizing tricyanometallate building blocks. The chains were further linked via long ditopic ligand to form two dimensional compounds. With the alignment of chains fixed by the rigid ditopic linker, the intrachain magnetic interactions between FeⅢ and MnⅡ could be further tuned via changing the capping ligand of FeⅢ ions.
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