Citation: ZONG Guang-Cai, REN Ning, ZHANG Jian-Jun, QI Xiao-Xia, GAO Jie, ZHANG Da-Hai. Hydrothermal Syntheses, Crystal Structures, Luminescence, Thermal Stabilities and Bacteriostatic Activities of Two Lanthanide Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1425-1432. doi: 10.11862/CJIC.2015.176 shu

Hydrothermal Syntheses, Crystal Structures, Luminescence, Thermal Stabilities and Bacteriostatic Activities of Two Lanthanide Complexes

ZONG Guang-Cai ^1,2 ,
REN Ning ^3,, ,
ZHANG Jian-Jun ^1,2,, ,
QI Xiao-Xia ^1,2 ,
GAO Jie ^1,2 ,
ZHANG Da-Hai ³

1.
1 Testing and Analysis Center, Hebei Normal University, Shijiazhuang 050024, China;
2.
2 College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China;
3.
3 College of Chemical Engineering& Material, Handan College, Handan, Hebei 056005, China

Corresponding author: REN Ning, ZHANG Jian-Jun,
Received Date: 13 March 2015
Available Online: 20 April 2015
Fund Project: 国家自然科学基金(No.21073053、21473049) (No.21073053、21473049) 河北省自然科学基金(No.B2012205022)资助项目。 (No.B2012205022)

Two lanthanide complexes [Ln(3,4-DFBA)₃(phen)(H₂O)]2(H₂O)₂ (Ln=Sm (1), Ho (2); 3,4-DFBa=3,4-difluorobenzoate, phen=1,10-phenanthroline) were prepared by hydrothermal method. Their structures were determined by single-crystal X-ray diffraction method. The structures of complexes 1 and 2 are isostructural with the coordination number of eight. They crystallized in the triclinic space group P1. The 2D layered structure is formed by intermolecular forces of adjacent two binuclear molecules. The title complexes were characterized by elemental analysis, IR, UV, XRD, and so on. The thermal stability of the complexes was tested using TG-DTG technology. The luminescent property of complex 1 had been explored. Besides, the bacteriostatic activities of the two complexes to candida albicans, Gram negative bacteria (escherichia coli) and Gram positive bacteria (staphylococcus aureus) were also studied.
- lanthanides;3,4-difluorobenzoic acid;thermal analysis;luminescence;bacteriostatic activity;crystal structure
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