Citation: ZONG Guang-Cai, REN Ning, ZHANG Jian-Jun, QI Xiao-Xia, GAO Jie, ZHANG Da-Hai. Hydrothermal Syntheses, Crystal Structures, Luminescence, Thermal Stabilities and Bacteriostatic Activities of Two Lanthanide Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1425-1432. doi: 10.11862/CJIC.2015.176
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Two lanthanide complexes [Ln(3,4-DFBA)3(phen)(H2O)]2(H2O)2 (Ln=Sm (1), Ho (2); 3,4-DFBa=3,4-difluorobenzoate, phen=1,10-phenanthroline) were prepared by hydrothermal method. Their structures were determined by single-crystal X-ray diffraction method. The structures of complexes 1 and 2 are isostructural with the coordination number of eight. They crystallized in the triclinic space group P1. The 2D layered structure is formed by intermolecular forces of adjacent two binuclear molecules. The title complexes were characterized by elemental analysis, IR, UV, XRD, and so on. The thermal stability of the complexes was tested using TG-DTG technology. The luminescent property of complex 1 had been explored. Besides, the bacteriostatic activities of the two complexes to candida albicans, Gram negative bacteria (escherichia coli) and Gram positive bacteria (staphylococcus aureus) were also studied.
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