Citation: CHEN Hong, YU Min, LIU Guang-Xiang. Syntheses and Crystal Structures of Nickel(Ⅱ) and Cadmium(Ⅱ) Coordination Polymers Constructed by Benzene-1,4-dioxydiacetate and 4,4-Bis(imidazole-l-yl)diphenyl Ether[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1261-1268. doi: 10.11862/CJIC.2015.170 shu

Syntheses and Crystal Structures of Nickel(Ⅱ) and Cadmium(Ⅱ) Coordination Polymers Constructed by Benzene-1,4-dioxydiacetate and 4,4-Bis(imidazole-l-yl)diphenyl Ether

1.
1 School of Chemical Engineering and Life Science, Chaohu University, Chaohu, Anhui 238000, China;
2.
2 School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: LIU Guang-Xiang,
Received Date: 1 March 2015
Available Online: 31 March 2015
Fund Project: 国家自然科学基金(No.21271106) (No.21271106)教育部科学技术重点项目(No.210102)资助。 (No.210102)

Two coordination polymers, [Ni(BDOA)(BIDPE)(H₂O)]_n (1) and [Cd(BDOA)_0.5(BIDPE)Cl]_n (2), (H₂BDOA=benzene-1,4-dioxydiacetic acid and BIDPE=4,4'-bis(imidazole-l-yl)diphenyl ether), have been synthesized and characterized by IRspectroscopy, elemental analysis and single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1 with a=0.93497(8) nm, b=1.03231(9) nm, c=1.35291(12) nm, α=96.3980(10)°, β=90.7290(10)°, γ=102.0270(10) °, V=1.26831(19) nm³, Z=2, M_w=603.22, D_c=1.580 g·cm^-3, μ=0.827, F(000)=624, R₁=0.0395, wR₂=0.0895(I>2σ(I)). Complex 2 belongs to triclinic, space group P1 with a=1.01751(7) nm, b=1.04299(7) nm, c=1.17338(8) nm, α=68.7230(10)°, β=71.8260(10)°, γ=76.0910(10)°, V=1.09105(13) nm³, Z=2, M_w=562.26, D_c=1.711 g·cm^-3, μ=1.163, F(000)=562, R₁=0.0210, wR₂=0.0537(I>2σ(I)). Structural analyses reveal that complex 1 exhibits a two-dimensional (2D) corrugated layer structure, whereas complex 2 possesses a one-dimensional (1D) chain structure which is generated by joining binuclear Cd₂ units by BIDPEand BDOAligands. The results show that the nature of metal ions plays an important role in governing the molecular frameworks. The photochemical properties of two complexes have also been studied.
- coordination polymer;bis(imidazole) ligands;polycarboxylate;crystal structure
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