Citation: Goudarziafshar Hamid, Yousefi Somaieh, Abbasityula Yunes, Dušek Michal, Eigner Václav, Rezaeivala Majid, Özbek Neslihan. Complexation of 1,3-Dimorpholinopropane with Hg(Ⅱ) and Zn(Ⅱ) Salts: Syntheses, Crystal Structures and Antibacterial Studies[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1076-1084. doi: 10.11862/CJIC.2015.164 shu

Complexation of 1,3-Dimorpholinopropane with Hg(Ⅱ) and Zn(Ⅱ) Salts: Syntheses, Crystal Structures and Antibacterial Studies

1.
1 Department of Chemistry, Faculty of Science, Sayyed Jamaleddinasadabadi University, Asadabad, Iran;
2.
2 Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516 Ilam, Iran;
3.
3 Department of Chemistry, Lorestan University, Khorramabad, Iran;
4.
4 Institute of Physics AS CR, v.v.i., Na Slovance 2, 182 21 Prague 8, Czech Republic;
5.
5 Department of Chemical Engineering, Hamedan University of Technology, P.O. Box 65155 Hamedan, Iran;
6.
6 Department of Primary Education, Faculty of Education, Ahi Evran University, 40100 Krsehir, Turkey

Corresponding author: Goudarziafshar Hamid,
Received Date: 26 January 2015
Available Online: 30 March 2015
Fund Project: Crystallography part was supported by the project (No.14-03276S) of the Czech Science Foundation. (No.14-03276S)

Two Hg(Ⅱ) (1) and Zn(Ⅱ) (2) complexes with general formulation M(DMP)Cl₂ where DMP=1,3-dimorpholinopropane were synthesized and structurally characterized by physicochemical methods and single crystal X-ray diffraction. An X-ray structural analysis shows that in both complexes Hg and Zn are coordinated by two nitrogen and two chlorine atoms in a form of distorted tetrahedron. The ligand and related complexes have antibacterial activity against three Gram-positive bacteria (S. epidermidis ATCC25923, E. faecalis ATCC23212 and S. epidermidis ATCC34384), and also against the three Gram-negative bacteria (E. coli ATCC25922, P. aeruginosa ATCC27853 and K. pneumonia ATCC70063). The results revealed that in some cases the antibacterial activity of Hg(Ⅱ) complex exceeded the one of sulfisoxazole used as a standard.
- crystal structure;1,3-dimorpholinopropane;antibacterial activity;Hg(Ⅱ) complex;Zn(Ⅱ) complex
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