Citation: QI Dan-Dan, ZHANG Fang, JIANG Da-Guang, QIN De-Cai, ZHANG Xiao-Gang. Fe₂O₃ Nanoparticles Prepared by Solid-State Thermolysis of Fe-Based Coordination Polymer and Their Enhanced Lithium Storage Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1171-1176. doi: 10.11862/CJIC.2015.159 shu

Fe₂O₃ Nanoparticles Prepared by Solid-State Thermolysis of Fe-Based Coordination Polymer and Their Enhanced Lithium Storage Properties

1.
College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, Nanjing 210016, China

Received Date: 20 January 2015
Available Online: 7 March 2015
Fund Project: 江苏省自然科学基金(No.BK2011740) (No.BK2011740)

α-Fe₂O₃ nanoparticles with uniform size were synthesized via a complex-precursor strategy. First, iron ion-based coordination polymer was synthesized via a solvothermal method by using p-benzene-dicarboxylic acid (p-H₂bdc) as ligand. Second, α-Fe₂O₃ nanoparticles with uniform size were prepared via a solid state pyrolysis procedure. The synthesized coordination polymer and Fe₂O₃ product were characterized by XRD, FT-IR, SEM and TEM respectively. When used as anode material for lithium-ion batteries, the Fe₂O₃ electrode can deliever a stable reversible capacity of 530 mAh·g^-1 after 50 charge-discharge cycles at a current density of 0.1 A·g^-1, which showed a higher specific capacity and superior cycle stability.
- α-Fe₂O₃;coordination polymer;solid-state thermolysis;lithium-ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142

Fe2O3 Nanoparticles Prepared by Solid-State Thermolysis of Fe-Based Coordination Polymer and Their Enhanced Lithium Storage Properties

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通讯作者: 陈斌, bchen63@163.com

Fe₂O₃ Nanoparticles Prepared by Solid-State Thermolysis of Fe-Based Coordination Polymer and Their Enhanced Lithium Storage Properties