Citation: ZHANG Fu-Xing, KUANG Dai-Zhi, FENG Yong-Lan, WANG Jian-Qiu, YU Jiang-Xi, JIANG Wu-Jiu, ZHU Xiao-Ming. Syntheses, Crystal Structures and Properties of the Tetra(o-fluorobenzyl)tin and the Tribenzyltin Ferrocenecarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1194-1200. doi: 10.11862/CJIC.2015.157 shu

Syntheses, Crystal Structures and Properties of the Tetra(o-fluorobenzyl)tin and the Tribenzyltin Ferrocenecarboxylate

1.
Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China

Corresponding author: ZHANG Fu-Xing,
Received Date: 11 March 2015
Available Online: 27 March 2015
Fund Project: 湖南省自然科学基金(No.13JJ3112) (No.13JJ3112)湖南省科技计划(No.2013TZ2025) (No.2013TZ2025)湖南省高校创新平台开放基金(No.13K105) (No.13K105)

The tetra(o-fluorobenzyl)tin (1) and the tribenzyltin ferrocenecarboxylate (2) have been synthesized. The crystal structures of the complexes were determined by X-ray diffraction. The crystal 1 belongs to tetragonal space group I4₁/a with a=1.96794(16) nm, b=1.96794(16) nm, c=0.59316(5) nm, V=2.2972(3) nm³, Z=4, D_c= 1.605 g·cm^-3, μ(MoKα)=11.58 cm^-1,F(000)=1112, R₁=0.0208, wR₂=0.0576. The crystal 2 belongs to monoclinic space group P2₁/n with a=1.59354(12) nm, b=1.00723(8) nm, c=1.70026(13) nm, β=91.001(10)°, V=2.7286(4) nm³, Z=4, D_c=1.521 g·cm^-3, μ(MoKα)=14.74 cm^-1, F(000)=1256, R₁=0.0384, wR₂=0.0952. The stabilities, some frontier molecular orbital energies and composition characteristics of some frontier molecular orbital of the complexes have been investigated by quantum chemistry calculation. Further more, thermal stability and anticancer activity of the complexes were tested.
- tetra(o-fluorobenzyl)tin;tribenzyltin ferrocenecarboxylate;synthesis;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142