Citation: CUI Yang-Zhe, GENG Wen-Xiao, QIU Qi-Ming, GAO Sen, LIU Min, LI Zhong-Feng, JIN Qiong-Hua. Syntheses, Crystal Structures and Spectroscopic Properties of Two Silver(Ⅰ) Complexes with Heterocyclic Thione[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1224-1230. doi: 10.11862/CJIC.2015.156
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Two silver(Ⅰ) complexes with heterocyclic thione, [AgBr(PPh3)2(BTZT)]2 (1) and [Ag2Cl2(PPh3)2(BTZT)2]·CH3OH (2) (PPh3=triphenylphosphine; BTZT=benzothiazoline-2-thione) have been synthesized and characterized by IR, single-crystal X-ray diffraction, fluorescence spectrum and 1H NMR spectroscopy. 1 and 2 are obtained by the reactions of AgX (X=Cl, Br) with PPh3 in the presence of 2-mercaptobenzothiazole (MBT) in mixed solvent (CH3OH/CH2Cl2). The MBTligand possesses chemically active groups (-N=C(-SH)), so MBTligand can transform into BTZTligand. Structure analysis shows that there exist two same molecular structures in complex 1, but they have different bond lengths and bond angles. Complex 2 consists of inversion symmetric dimers with a diamond-shaped Ag2Cl2 group at the center, and two adjacent [AgCl(PPh3)(BTZT)] units are bridged by two Cl atoms.
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