Citation: LU Yong-Juan, JIA Jun-Hong. Preparation and Photoelectrical Properties of Bi2S3 Quantum Dots Sensitized TiO2 Nanorod-Arrays[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1091-1098. doi: 10.11862/CJIC.2015.155
-
Hydrothermally synthesized TiO2 nanorod arrays on FTO glass substrates were functionalized with uniform Bi2S3 quantum dots by CBD method combined with self-assembled monolayers(SAMs). The surface morphology, structure, optical and photoelectrochemical behaviors of the TiO2/Bi2S3 nanorod arrays are considered. The results that uniform Bi2S3 thin films were deposited on the surface of TiO2 nanorods modified by APTS SAMs. The key of the technology is that the APTS SAM possessing -NH2 functional groups can be employed to control nucleation. Moreover, the deposition time of Bi2S3 thin film plays a key role in the visible light absorption as well as photoelectric response of TiO2/Bi2S3 nanorod arrays. It reveals that, with the increase of the deposition time, the Jsc of composite thin film first increased and then decreased, and a Jsc maximum value of 0.13 mA·cm-2 reached at 20 min deposition of Bi2S3. The increase of Jsc for the initial deposition time could be interpreted as the result of enhanced absorption in the visible light range. Further increase the deposition time resulted in an obvious decrease in Jsc. This phenomenon might be attributed to Bi2S3 overloading on the surface of TiO2 resulted in aggregations and conglomerations, leading to more surface defects and recombination of photoexcited carrier.
-
-
[1]
[1] Falaras P, Gratzel M, Nazeemddin M, et al. J. Electrochem. Soc., 1993,140:92-94
-
[2]
[2] Barbe C J, Arendse F, Comte P. J. Am. Ceram. Soc., 1997, 80:3157-3171
-
[3]
[3] Mor G K, Shankar K, Paulose M, et al. Nano Lett., 2006,6: 215-218
-
[4]
[4] Kai Z, Nathan R N, Miedaner A, et al. Nano Lett., 2007,7: 69-74
-
[5]
[5] Zhao J, Wang X, Chen R. Mater. Lett., 2005,59:2329-2332
-
[6]
[6] Adachi M, Murata Y, Okada I, et al. J. Electrochem. Soc., 2003,150:G488-G493
-
[7]
[7] Paulose M, Shankar K, Varghese O K, et al. Nanotechnology, 2006,17:1446-1448
-
[8]
[8] Paulose M, Varghese O K, Mor G K, et al. Nanotechnology, 2006,17:398-402
-
[9]
[9] Adachi M, Murata Y, Harada M, et al. Chem. Lett., 2000,29: 942-943
-
[10]
[10] Chu S Z, Inoue S, Wada K, et al. J. Phys. Chem. B, 2003, 107:6586-6589
-
[11]
[11] Zhang Z, Shimizu T, Senz S. Adv. Mater., 2009,21:2824-2828
-
[12]
[12] Michailowski A, Almlwai D, Cheng G S, et al. Chem. Phys. Lett., 2001,349:1-5
-
[13]
[13] Wu J J, Yu C C. J. Phys. Chem. B, 2004,108:3377-3379
-
[14]
[14] Feng X J, Shankar K, Varghese O K, et al. Nano Lett., 2008,8:3781-3786
-
[15]
[15] Liu B, Aydil E S. J. Am. Chem. Soc., 2009,131:3985-3990
-
[16]
[16] Robel I, Subramanian V, Kuno M, et al. J. Am. Chem. Soc., 2006,128:2385-2393
-
[17]
[17] LIU Fei-La(刘非拉), XIAO Peng(肖鹏), ZHOU Ming(周明), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(5): 861-872
-
[18]
[18] Nozik A J, Beard M C, Luther J M, et al. Chem. Rev., 2010, 110:6873-6890
-
[19]
[19] Vogel R, Hoyer P, Weller H. J. Phys. Chem., 1994,98:3183-3188
-
[20]
[20] LI Jing(李静). Thesis for the Master of Hubei University(湖 北大学硕士学位论文), 2013.
-
[21]
[21] Peter L M, Waggett J P, et al. J. Phys. Chem. B, 2003,107: 8378-8381
-
[22]
[22] Roemermahler J, Bremer F J. Adv. Mater., 1995,7:7-9
-
[23]
[23] Aizenberg J, Black A J, Whitesides G H. J. Am. Chem. Soc., 1999,121:4500-4509
-
[24]
[24] Liufu S, Chen L D. J. Phys. Chem. C, 2008,112:12085-12088
-
[25]
[25] Liufu S, Chen L D, et al. J. Phys. Chem. B, 2006,110:24054 -24061
-
[26]
[26] Lu Y, Jia J, Yi G. CrystEngComm, 2012,14:3433-3440
-
[27]
[27] Cao C, Hu C, Wang X. Sensor Actuat B, 2011,156:114-119
-
[28]
[28] Coughlin K M, Nevins J S, Watson D F. ACS Appl. Mater. Interfaces, 2013,5:8649-8654
-
[29]
[29] ZHU Gang-Qiang(朱刚强), HUANG Xi-Jin(黄锡金), FEN Bo(冯波), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(11):2041-2046
-
[30]
[30] Wang H, McNellis E R, Kinge S, et al. Nano Lett., 2013,13: 5311-5315
-
[31]
[31] Ardalan P, Brennan T P, Bakke J R, et al. ACS Nano, 2011,5: 1495-1504
-
[32]
[32] Cai F G, Yang F, Jia Y F, et al. J. Mater. Sci., 2013,48: 6001-6007
-
[33]
[33] Nasr C, Hotchandani S, Kim W Y, et al. J. Phys. Chem. B, 1997,101:7480-7487
-
[34]
[34] Sant P A, Kamat P V. Phys. Chem. Chem. Phys., 2002,4: 198-203
-
[35]
[35] Yang L, Luo S, Liu R, et al. J. Phys. Chem. C, 2010,114: 4783-4789
-
[1]
-
-
[1]
Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs3Bi2X9 (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
-
[2]
Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
-
[3]
Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
-
[4]
Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
-
[5]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[6]
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
-
[7]
Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
-
[8]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[9]
Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C3N4/Ti3C2Tx Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
-
[10]
Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO2 catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
-
[11]
Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
-
[12]
Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO2/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
-
[13]
Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
-
[14]
Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
-
[15]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[16]
Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO2 nanotube array modified Ti-based Ni-Sb co-doped SnO2 anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
-
[17]
Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO2/NH2−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
-
[18]
Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu2O/Bi2MoO6 Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
-
[19]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[20]
Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb2O6/Nitrogen-Enriched C3N5 S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(313)
- HTML views(61)