Citation: XIAO Hui, SUN Li-Ping, ZHAO Hui, HUO Li-Hua, Jean-Marc Bassat, Aline Rougier, Sébastien Fourcade, Jean-Claude Grenier. Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1139-1144. doi: 10.11862/CJIC.2015.153 shu

Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs

1.
1 Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China;
2.
2 CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. A. Schweitzer, F-33608 Pessac-Cedex, France

Received Date: 13 December 2014
Available Online: 23 March 2015
Fund Project: 国家自然科学基金(No.51302069,51372073) (No.51302069,51372073)高等学校博士学科点专项科研基金(No.20132301110002) (No.20132301110002)

LaBiMn₂O₆(LBM) cathode for IT-SOFCs (intermediate temperature solid oxide fuel cells) has been prepared by solid state reaction and studied by XRDand EISspectrum,respectively. The results show that LBM has no reaction with Ce_0.7Bi_0.3O_1.85(CBO) electrolyte at 1000 ℃ for 12 h. AC impedance spectroscopy and DC polarization measurements are used to study the electrode performances. The polarization resistance decreases with temperature and reaches 0.71 Ω·cm² at 700 ℃ in air. Oxygen partial pressure study indicated that charge transfer process is the major rate limiting step for LaBiMn₂O₆ cathode from 600 to 700 ℃. The LaBiMn₂O₆ cathode exhibits the lowest overpotential of 85 mVunder current density of 216 mA·cm^-2 at 700 ℃ in air. This preliminary work showes that LaBiMn₂O₆ material may be potential cathodes for IT-SOFCs.
- intermediate temperature solid oxide fuel cells (IT-SOFCs);cathode material;LaBiMn₂O₆;electrode reaction
1. [1]
  [1] Adler S B. Chem. Rev., 2004,104:4791-4843
2. [2]
  [2] Kim G, Wang S, Jacobson A J, et al. J. Mater. Chem., 2007, 17:2500-2505
3. [3]
  [3] Tarancón A, Skinner S J, Chater R J, et al. J. Mater. Chem., 2007,17:3175-3181
4. [4]
  [4] Yoo S, Shin J Y, Kim G. J. Mater. Chem., 2011,21:439-443
5. [5]
  [5] Burriel M, Peña-Martínez J, Chater R J, et al. J. Mater. Chem., 2012,24:613-621
6. [6]
  [6] Zhang K, Ge L, Ran R, et al. Acta Mater., 2008,56:4876 -4889
7. [7]
  [7] Jin M F, Zhang X L, Qiu Y E, et al. J. Alloys Compd., 2010,494:359-361
8. [8]
  [8] Kim J H, Manthiram A. J. Electrochem. Soc., 2008,155:385 -390
9. [9]
  [9] Zhou Q J, Wang F, Shen Y, et al. J. Power Sources, 2010, 195:2174-2181
10. [10]
  [10] Chen D J, Ran R, Zhang K, et al. J. Power Sources, 2009, 188:96-105
11. [11]
  [11] Albert Tarancón, Mónica Burriel, José Santiso, et al. J. Mater. Chem., 2010,20:3799-3813
12. [12]
  [12] Taskin A A, Lavrov A N, Yoichi Ando. Appl. Phys. Lett., 2005,86(9):091910-3
13. [13]
  [13] Liu Y. J. Alloys Compd., 2009,477:860-862
14. [14]
  [14] Zhang X T, Hao H S, He Q L. Physica B, 2007,394:118 -121
15. [15]
  [15] Xue J F, Shen Y, He T M. J. Power Sources, 2011,196: 3729-3735
16. [16]
  [16] Martin C, Maignan A, Pelloquin D. Appl. Phys. Lett., 1997, 71:1421-1423
17. [17]
  [17] Maignan A, Martin C, Pelloquin D, et al. J. Solid State Chem.,1999,142(2):247-260
18. [18]
  [18] Chen D, Wang F C, Shi H G. Electrochim. Acta, 2012,78: 466-474
19. [19]
  [19] Lu K, Shen F Y, Rose Roberts, et al. J. Power Sources, 2014,268:379-387
20. [20]
  [20] Sun L P, Huo L H, Zhao H. J. Power Sources, 2008,179:96 -100
21. [21]
  [21] Li Q, Sun L P, Zeng X. J. Power Sources, 2013,238:11-16
22. [22]
  [22] Wang Y X, Zhao X Y, Lü S Q. Ceram. Int., 2014,40:11343 -11350
23. [23]
  [23] Zhao H, Feng S H, Xu W. Mater. Res. Bull., 2000,35(15): 2379-2386
24. [24]
  [24] Asish K K, Pralong V, Caignaert V, et al. J. Mater. Chem., 2007,17:3347-3353
25. [25]
  [25] Daroukha M A, Vashooka V V, Ullmanna H, et al. Solid State Ionics, 2003,158:141-150
26. [26]
  [26] Nagde K R, Bhoga S S. Ionics, 2009,15:571-578
27. [27]
  [27] Jiang S P. J. Power Sources, 2003,124:390-402
28. [28]
  [28] Gao Z, Liu X M, Bergman B, et al. J. Power Sources, 2011,196:9195-9203
29. [29]
  [29] Kim J D, Kim G D, Moon J W, et al. Solid State Ionics, 2001,143:379-389
1. [1]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
9. [9]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
10. [10]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
11. [11]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
12. [12]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
13. [13]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
14. [14]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
15. [15]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
16. [16]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
17. [17]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
18. [18]
  Shengwen Guan , Zhaotong Wei , Ningxu Han , Yude Wei , Bin Xu , Ming Wang , Junjuan Shi . Construction of metallo-complexes with 2,2′:6′,2″-terpyridine substituted triphenylamine in different modified positions and their photophysical properties. Chinese Chemical Letters, 2024, 35(7): 109348-. doi: 10.1016/j.cclet.2023.109348
19. [19]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
20. [20]
  Yubang Li , Xixi Hu , Daiqian Xie . The microscopic formation mechanism of O + H2 products from photodissociation of H2O. Chinese Journal of Structural Chemistry, 2024, 43(5): 100274-100274. doi: 10.1016/j.cjsc.2024.100274

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(350)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Properties of LaBiMn2O6 Cathode for IT-SOFCs

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Properties of LaBiMn₂O₆ Cathode for IT-SOFCs