Citation: QIAN Yan-Tao, PENG Ye-Dong, ZHANG Wen-Wei. Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 857-864. doi: 10.11862/CJIC.2015.148 shu

Syntheses, Structures and Properties of Metal-Organic Frameworks Based on Imidazolyl-Aromatic Multi-Carboxylate Acid Ligands

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: ZHANG Wen-Wei,
Received Date: 27 January 2015
Available Online: 27 March 2015
Fund Project: 国家自然科学基金(No.51173075)资助项目。 (No.51173075)

Three metal-organic frameworks, namely [PrL(HL)(H₂O)₂]·H₂O (1), Er(H_0.5L)₂ (2), and [CoL(H₂O)₂]·H₂O (3) (H₂L=5-(1H-imidazol-1-yl)isophthalic acid), have been synthesized under hydrothermal condition. Single crystal X-ray diffraction indicates that all the three complexes belong to the monoclinic space group P2₁/c. The Pr³⁺ ions in 1 are nine-coordinated, while the Er³⁺ ions in 2 and Co²⁺ ions in 3 are both six-coordinated. In the lanthanide complex 1 and 2, the nitrogen atom does not coordinate with any metal ions. Complex 1 shows a 2D folding framework, while complex 2 exhibits a 3D network. In the transition metal complex 3, the nitrogen atom coordinates with Co²⁺, which helps to form a flat 2D framework. Complex 1 and 3 are further packed into 3D framework by the intermolecular π-π interactions. All the three complexes display good thermal stability.
- metal-organic framework;transition metal;lanthanide;hydrothermal synthesis;crystal structure
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