Citation: ZHANG Shu-Fang, XIONG Fang, LIU Yu-Fen, HE Zhan, LIANG Yue, XUE Jun-ru, JING Lin-Hai, QIN Da-Bin. Syntheses and Structures of Two 3D Metal NHCs Based on Flexible Functionalized Bibenzimidazole[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1027-1033. doi: 10.11862/CJIC.2015.147 shu

Syntheses and Structures of Two 3D Metal NHCs Based on Flexible Functionalized Bibenzimidazole

1.
Key Laboratory of Chemical Synthesis and Pollution Control of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China

Corresponding author: QIN Da-Bin,
Received Date: 12 December 2014
Available Online: 6 February 2015
Fund Project: 国家自然科学基金(No.21102117) (No.21102117)四川省合成与污染控制重点实验室基金(No.CSPC2014-4-1)资助项目。 (No.CSPC2014-4-1)

[Hg(C₃₂H₂₈N₄O)](CH₃COO)(PF₆)₂ (1) and [NiCl(C₃₀H₂₈N₆O)]PF₆ (2) have been synthesized based on₁,1'-bisbenzyl-3,3'-oxybis(ethane-2,1-diyl)-dibenzimidazolium-dihexafluorophosphate ligand (L1) and 1,1'-bis (pyridine-2-ylmethyl)-3,3'-oxybis(ethane-2,1-diyl)-dibenzimidazolium-dihexafluorophosphate ligand (L2) and structurally characterized. The complex 1 is a rare three valence state mercury NHC and crystallizes in the P2₁/c space group with monoclinic crystal system. The complex 2 crystallizes in the P2₁/n space group with monoclinic crystal system. There are O-H…F, C-H…F, C-H…Cl, C-H…π, P-F…π hydrogen bonds interactions and π…π stacking interactions contributing to 3D supramolecular structure of 1 and 2.
- flexible dibenzimidazolium;metal NHC;3D supramolecular structure
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沈阳化工大学材料科学与工程学院沈阳 110142