Citation: LI Ting, LI Xin, ZHOU Shang-Yong, TIAN Li. Copper(Ⅱ) Complexes Based on 5-Sulfoisophthalate and Bis(1,2,4-triazol-1-yl)alkanes: Syntheses, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1215-1223. doi: 10.11862/CJIC.2015.145
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The reaction of copper(Ⅱ) nitrate with flexible bis(1,2,4-triazol-1-yl)alkanes and rigid ligand 5-sulfoisophthalic acid monosodium salt (NaH2sip) affords three complexes [Cu0.5(btm)(H2O)](H2sip)·H2O}n (1, btm=bis(1,2,4-triazol-1-yl)methane), {[Cu(btp)2(H2sip)(H2O)](NO3)·4H2O}n (2, btp=1,3-bis(1,2,4-triazol-1-yl)propane), and {[Cu(btb)2(Hsip)]n (3, btb=1,4-bis(1,2,4-triazol-1-yl)butane). Compound 1 contains one-dimensional (1D) double-strained chains. Compound 2 contains two-dimensional (2D) rectangular networks with (4,4) topology, in which the 2D planar nanogrid networks stacked in a step stacking fashion.3 is also 2D layers, in which double-strained chains [Cu(btb)]n are connected into 2D layer architectures by the μ2-Hsip2- linkers. The three compounds also are characterized by Elemental analysis, EPR, and thermal stability.
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