Citation: ZHONG Di-Chang, LU Wen-Guan. Syntheses and Characterization of Two Three-Dimensional Layered-Pillared Inorganic-Organic Hybrid Materials Constructed from Inorganic Cadmium Sulfate Layers and in situ Generated Organic 5-(Pyridyl)tetrazolate Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1177-1184. doi: 10.11862/CJIC.2015.144 shu

Syntheses and Characterization of Two Three-Dimensional Layered-Pillared Inorganic-Organic Hybrid Materials Constructed from Inorganic Cadmium Sulfate Layers and in situ Generated Organic 5-(Pyridyl)tetrazolate Ligands

ZHONG Di-Chang ¹ ,
LU Wen-Guan ^2,,

1.
1 College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, Jiangxi 341000, China;
2.
2 Department of Chemistry, Shaoguan University, Shaoguan, Guangdong 512005, China

Corresponding author: LU Wen-Guan,
Received Date: 1 February 2014
Available Online: 18 March 2015
Fund Project: 国家自然科学基金资助项目(No.21071099,21363001) (No.21071099,21363001)广东省普通高校特色创新(自然科学类)项目(No.2014KTSCX169)。 (自然科学类)项目(No.2014KTSCX169)

Hydrothermal reactions of CdSO₄ and NaN₃ with 4-cyanopyridine or 3-cyanopyridine yielded two three-dimensional layered-pillared inorganic-organic hybrid materials based on mixed ligands of sulfate and in situ synthesized 5-(4-pyridyl)tetrazolate(4-ptz^-) or 5-(3-pyridyl)tetrazolate(3-ptz^-), respectively, namely, [Cd₂(H₂O)(OH)(SO₄)(4-ptz)]_n (1) and [Cd₂(OH)(SO₄)(3-ptz)]_n (2), which have been structurally characterized by elemental analysis (EA), infrared spectroscopy (IR), thermogravimetric analysis (TGA), single-crystal and powder X-ray diffraction. In 1 and 2, each Cd(Ⅱ) ion is six-coordinated with a distorted octahedral coordination geometry, which are connected through SO₄^2- and OH^-, leading to an infinite two-dimensional cation layer structure of [Cd₂(H₂O)(OH)(SO₄)]_nⁿ⁺(1) or [Cd₂(OH)(SO₄)]_nⁿ⁺(2). These adjacent two-dimensional cation layers are further linked by 4-ptz^- (1) or 3-ptz^- (2) pillared ligands to form infinite three-dimensional layered-pillared inorganic-organic hybrid frameworks architecture of 1 and 2, respectively. In addition, the results of photoluminescent measurements in the solid state at room temperature indicate that 1 and 2 all exhibit intense fluorescent emissions at λ_max=481 nm and 489 nm when excited at 350 nm, respectively.
- organic-inorganic hybrid materials;5-(pyridyl)tetrazole;mixed-ligand;crystal structure;fluorescence
1. [1]
  [1] Xue X, Wang X S, Wang L Z, et al. Inorg. Chem., 2002,41: 6544-6546
2. [2]
  [2] Tao J, Ma Z J, Huang R B, et al. Inorg. Chem., 2004,43: 6133-6135
3. [3]
  [3] He X, Lu C Z, Yuan D Q. Inorg. Chem., 2006,45:6760-5766
4. [4]
  [4] Pachfule P, Banerjee R. Cryst. Growth Des., 2011,11:5176-5181
5. [5]
  [5] Chang C C, Huang Y C, Huang S M, et al. Cryst. Growth Des., 2012,12:3825-3828
6. [6]
  [6] Mautner F A, Gspan C, Gatterer K, et al. Polyhedron, 2004, 23:1217-1224
7. [7]
  [7] Wang X S, Tang Y Z, Huang X F, et al. Inorg. Chem., 2005,44:5278-5285
8. [8]
  [8] Tang Y Z, Wang G X, Ye Q, et al. Cryst. Growth Des., 2007,7:2382-2386
9. [9]
  [9] Yang Y T, Zhao F H, Che Y X, et al. Inorg. Chem. Commun., 2011,14:1855-1859
10. [10]
  [10] Nasani R, Saha M, Mobin S M, et al. Dalton Trans., 2014,43:9944-9954
11. [11]
  [11] Zhong D C, Lin J B, Lu W G, et al. Inorg. Chem., 2009,48: 8656-8658
12. [12]
  [12] Liu D S, Huang X H, Huang C C, et al. J. Solid State Chem., 2009,182:1899-1906
13. [13]
  [13] Song W C, Pan Q H, Song P C, et al. Chem. Commun., 2010, 46:4890-4892
14. [14]
  [14] Song W C, Tao J, Hu T L, et al. Dalton Trans., 2011,40: 11955-11959
15. [15]
  [15] Yang E C, Liu Z Y, Wu X Y, et al. Chem. Commun., 2011, 47:8629-8631
16. [16]
  [16] Liu D S, Sui Y, Wang T W, et al. Dalton Trans., 2012,41: 5301-5306
17. [17]
  [17] Liu D S, Chen W T, Huang J G, et al. Inorg. Chem. Commun., 2013,36:174-178
18. [18]
  [18] Xiang J, Luo Y. Inorg. Chem. Commun., 2013,37:12-16
19. [19]
  [19] LU Wen-Guan(卢文贯), LIU Hong-Wen(刘宏文), YIN Xu-Guang(殷旭光), et al. Chem. J. Chinese Universities (高等学校化学学报), 2013,34(12):2691-2698
20. [20]
  [20] Liu Z Y, Zou H A, Hou Z J, et al. Dalton Trans., 2013,42: 15716-15725
21. [21]
  [21] Zhong D C, Lu W G, Deng J H. CrystEngComm, 2014,16: 4633-4640
22. [22]
  [22] Calahorro A J, Salinas-Castillo A, Fairen-Jimenez D, et al. Inorg. Chim. Acta, 2015,427:131-137
23. [23]
  [23] Zheng Y, Wang S H, Wu S F, et al. Inorg. Chem. Commun., 2015,53:20-22
24. [24]
  [24] Deng H, Qiu Y C, Liu Y H, et al. Chem. Commun., 2008, 2239-2241
25. [25]
  [25] GE Gen-Wu(戈根武), LIU Mei-Pin(刘美玭), NI Zhi-Gang (倪志刚), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011,32(3):644-649
26. [26]
  [26] ZHANG Deng (张登), LÜ Yun (吕赟), XU Xin (许新), et al. Chinese J. Inorg. Chem. (无机化学学报), 2012,28(6):1298 -1304
27. [27]
  [27] Ju W W, Zhang D, Zhu D R, et al. Inorg. Chem., 2012,51: 13373-13379
28. [28]
  [28] Wang W H, Tian H R, Zhou Z C, et al. Cryst. Growth Des., 2012,12:2567-2571
29. [29]
  [29] Xiang H, Lu W G, Zhang W X, et al. Dalton Trans., 2013, 42:867-870
30. [30]
  [30] WANG Hong-Xiang(万洪祥), JU Wei-Wei(鞠伟伟), ZHANG Yu(张宇), et al. Chinese J. Inorg. Chem. (无机化学学报), 2014,30(1):85-92
31. [31]
  [31] Yao Y L, Xue L, Che Y X, et al. Cryst. Growth Des., 2009,9:606-610
32. [32]
  [32] Liu D S, Huang G S, Huang C C, et al. Cryst. Growth Des., 2009,9:5117-5127
33. [33]
  [33] Wang T W, Liu D S, Huang C C, et al. Cryst. Growth Des., 2010,10:3429-3435
34. [34]
  [34] Paul A K, Sanyal U, Natarajan S. Cryst. Growth Des., 2010,10:4161-4175
35. [35]
  [35] Darling K, Ouellette W, Prosvirin A, et al. Cryst. Growth Des., 2012,12:2662-2672
36. [36]
  [36] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.
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