Citation: YANG Hong, WANG Hua-Hua, YANG Shu-Bao, ZHANG Hao, LIU Hai-Yang. Catalytic Styrene Oxidation by Iron Corroles Bearing Different Substituents[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 968-974. doi: 10.11862/CJIC.2015.141
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Four meso-substituted iron(Ⅳ) corroles having different number of pentafluorophenylor phenyl groups were synthesized and characterized by UV-Vis, NMR and MS. The catalytic styrene oxidation by these iron corroles using tert-butyl hydroperoxide (TBHP), iodosylbenzene (PhIO), hydrogen peroxide(H2O2) in acetonitrile was investigated. The effect of imidazole as axial ligand on the catalytic oxidation was also examined. The results indicate that the yields of the products depend on oxidants, catalysts and axial ligand. For TBHP, benzaldehyde is the major product. Styrene epoxide is the major product when using PhIOoxidant. All iron(Ⅳ) corroles studied cannot effectively catalyze styrene oxidation by using H2O2. Four iron corroles exhibit different activity order when using different oxidants, and the catalytic process may involve free radical and Fe(Ⅴ)-oxocorrole species. The axial coordination of F15C-Feby imidazole gives 1:2 complexes. Also, axial ligand imidazole has different effect on the oxidation product distribution when using different oxidants.
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