Citation: WANG Li-Zhen, XU Yong, FANG Hua, GAO Hai-Li. Effect of Glucose on the Performance of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ Synthesized by Sol-Gel Method[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 873-879. doi: 10.11862/CJIC.2015.140 shu

Effect of Glucose on the Performance of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ Synthesized by Sol-Gel Method

WANG Li-Zhen ^1,2,, ,
XU Yong ¹ ,
FANG Hua ¹ ,
GAO Hai-Li ¹

1.
1 Zhengzhou Institute of Light Industry, Zhengzhou 450002, China;
2.
2 Key Lab of Surface and Interface Science, Zhengzhou 450002, China

Corresponding author: WANG Li-Zhen,
Received Date: 25 December 2014
Available Online: 5 March 2015
Fund Project: 国家自然科学基金面上项目(No.21471135) (No.21471135)河南省基础与前沿技术研究重点项目(No.112300413216)资助。 (No.112300413216)

The cathode material Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ was synthesized by sol-gel method modified by glucose as carbon source. The structure, morphology and electrochemical performances of the as-prepared sample was studied by methods of XRD, SEM, EDS, BET, Laser Particle Size Analysis, cyclic voltammetry, galvanostatic charge-discharge and AC impedance. Test results showed that the distribution of particles became uniform and the sizes became smaller for the modification by glucose. The D₅₀ decreased from 11.56 to 9.94 μm. The specific surface area nearly doubled. The initial discharge specific capacity at 0.2C reached 183.4 mAh·g^-1 and 211.6 mAh·g^-1 after been activated by 0.05C for blank and compared groups, respectively. The capacity at 2C retained 62.2% and 77.6% of that at 0.2C for the two samples, respectively. After 50 cycles at 1C, the discharge specific capacities retained 133.3 mAh·g^-1 and 173.6 mAh·g^-1, and the capacity retention rates were 95.1% and 100% for the two samples, respectively. The initial irreversible capacity loss was reduced for the modification by glucose. The rate performance and cycle stability were obviously improved. The impedance of charge transfer and Warburg, and dispersion effect of the electric double layer were decreased. The crystal structure of the sample stayed unchanged.
- lithium ion battery;Li_1.2Ni_0.13Co_0.13Mn_0.54O₂;sol-gel method;glucose
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Effect of Glucose on the Performance of Li1.2Ni0.13Co0.13Mn0.54O2 Synthesized by Sol-Gel Method

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通讯作者: 陈斌, bchen63@163.com

Effect of Glucose on the Performance of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ Synthesized by Sol-Gel Method