Citation: YE Hong-De, XING Ze-Sheng, HU Jiu-Rong, PENG Hua-Nan, XIE Jia-Lin, LIU Lin-Hai. Reactivity of Half-Sandwich 16e Carborane Compound Me4CpCoS2C2B10H10 with Ferrocenyne Ketone[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1534-1538. doi: 10.11862/CJIC.2015.138
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o-Carborane reacts with n-butyllithium, sulfur powder and Me4CpCo(CO)I2 respectively to give the half-sandwich 16e carborane compound Me4CpCoS2C2B10H10 (1). The reaction of 1 with ferrocenyne ketone in dichloro-methane leads to the product {(Me4CpCoS2C2B10H10)[FcC(O)CHCCHCC(O)Fc]} (2) (Fc=ferrocenyl). 2 is a 1:2 adduct. The alkynone is twofold inserted into one Co-S bond of 2 in a head-tail mode. 1 and 2 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis. CCDC: 1045890, 1; 1045891, 2.
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