Advanced Search

Citation: YE Hong-De, XING Ze-Sheng, HU Jiu-Rong, PENG Hua-Nan, XIE Jia-Lin, LIU Lin-Hai. Reactivity of Half-Sandwich 16e Carborane Compound Me4CpCoS2C2B10H10 with Ferrocenyne Ketone[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1534-1538. doi: 10.11862/CJIC.2015.138 shu

Reactivity of Half-Sandwich 16e Carborane Compound Me4CpCoS2C2B10H10 with Ferrocenyne Ketone

  • 1.

    1. Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;

  • 2.

    2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

  • Corresponding author: YE Hong-De, 
  • Received Date: 28 January 2015
    Available Online: 20 March 2015

    Fund Project: 国家自然科学基金(No.21361022、21261020) (No.21361022、21261020)江西省教育厅2014年度普通本科高校大学生创新创业教育计划项目,南京大学配位化学 国家重点实验室第25批开发课题,第54批中国博士后科学基金面上基金(No.2013M541640)资助项目。 (No.2013M541640)

  • o-Carborane reacts with n-butyllithium, sulfur powder and Me4CpCo(CO)I2 respectively to give the half-sandwich 16e carborane compound Me4CpCoS2C2B10H10 (1). The reaction of 1 with ferrocenyne ketone in dichloro-methane leads to the product {(Me4CpCoS2C2B10H10)[FcC(O)CHCCHCC(O)Fc]} (2) (Fc=ferrocenyl). 2 is a 1:2 adduct. The alkynone is twofold inserted into one Co-S bond of 2 in a head-tail mode. 1 and 2 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis. CCDC: 1045890, 1; 1045891, 2.
  • 加载中
    1. [1]

      [1] Fox M A, Hughes A K. Coord. Chem. Rev., 2004,248:457-476

    2. [2]

      [2] Valliant J F, Guenther K J, King A S, et al. Coord. Chem. Rev., 2002,232,173-230

    3. [3]

      [3] Meng X, Wang F, Jin G X. Coord. Chem. Rev., 2010,254:1260-1272

    4. [4]

      [4] Herberhold M, Yan H, Milius W, et al. Angew. Chem. Int. Ed., 1999,38:3689-3691

    5. [5]

      [5] Liu S, Han Y F, Jin G X. Chem. Soc. Rev., 2007,36:1543-1560

    6. [6]

      [6] Zhang J S, Jin G X. Inorg. Chem. Commun., 2008,11:145-149

    7. [7]

      [7] Herberhold M, Yan H, Milius W, et al. Chem. Eur. J., 2002, 8:388-395

    8. [8]

      [8] Kim D H, Ko J, Park K, et al. Organometallics., 1999,18:2738-2740

    9. [9]

      [9] Xu B H, Peng X Q, Li Y Z, et al. Chem. Eur. J., 2008,14:9347-935

    10. [10]

      [10] Li Y G, Jiang Q B, Li Y Z, et al. Inorg. Chem., 2010,49:4-6

    11. [11]

      [11] Xu B H, Wu D H, Li Y Z, et al. Organometallics, 2007,26:4344-4349

    12. [12]

      [12] Wang Z J, Ye H D, Li Y G, et al. J. Am. Chem. Soc., 2013, 135:11289-11298

    13. [13]

      [13] Ye H D, Ding G Y, Xie M S, et al. Dalton Trans., 2011,40:2306-2313

    14. [14]

      [14] Barriga S, Marcos C F, Riant O, et al. Tetrahedron, 2002,58:9785-9792

    15. [15]

      [15] SAINT-Plus, Version 6.02. Bruker Analytical X-ray System, Madison, WI, 1999.

    16. [16]

      [16] Sheldrick G M. SADABS, An Empirical Absorption Correction Program. Bruker Analytical X-ray Systems, Madison, WI, 1996.

    17. [17]

      [17] Sheldrick G M. SHELXS 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1990.

    18. [18]

      [18] Sheldrick G M. SHELXL 97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    19. [19]

      [19] Zhang R, Zhu L, Lu Z Z, et al. Dalton Trans., 2012,41:12054-12063

    20. [20]

      [20] Bae J, Park Y, Ko J, et al. Inorg. Chim. Acta, 1999,289:141-148

    21. [21]

      [21] Ye H D, Xu B H, Xie M S, et al. Dalton Trans., 2011,40:6541-6546

    22. [22]

      [22] Li Y G, Ye H D, Guoyiqibayi G, et al. Sci. China Ser. B Chem., 2010,53(10):2129-2138

  • 加载中
    1. [1]

      Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006

    2. [2]

      Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077

    3. [3]

      Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385

    4. [4]

      Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

    5. [5]

      Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093

    6. [6]

      Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404

    7. [7]

      Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370

    8. [8]

      Zhengyu Zhou ,  Huiqin Yao ,  Youlin Wu ,  Teng Li ,  Noritatsu Tsubaki ,  Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010

    9. [9]

      Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    10. [10]

      Juntao Yan ,  Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024

    11. [11]

      Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

    12. [12]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    13. [13]

      Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388

    14. [14]

      Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

    15. [15]

      Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(254)
  • HTML views(35)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return