Citation: NI Bang-Qing, HUANG Jiang-Lei, ZHANG Ping-Bo, FAN Ming-Ming. Al-MCM-41 Immobilized Ionic Liquids Catalysts Containing Double-Acid Active Sites for Biodiesel Production[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 961-967. doi: 10.11862/CJIC.2015.131 shu

Al-MCM-41 Immobilized Ionic Liquids Catalysts Containing Double-Acid Active Sites for Biodiesel Production

1.
School of Chemical and Material Engineering, Jiangnan University, the Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, Wuxi, Jiangsu 214122, China

Corresponding author: FAN Ming-Ming,
Received Date: 30 January 2015
Available Online: 29 March 2015
Fund Project: 国家自然基金(No.21171057,21371059)与广东省自然基金(No.10351064101000000)资助项目。 (No.21171057,21371059)与广东省自然基金(No.10351064101000000)

The immobilized catalysts with double-acid active sites were synthesized by loading ionic liquids (ILs) on MCM-41 with different Si/Al molar ratios. The catalysts were characterized by XRD, FTIR, N₂ adsorption-desorption, thermogravimetric analysis and TEM, and the activities of catalysts were investigated by the transesterification of soybean oil with methanol for biodiesel synthesis as the probe reaction. The results demonstrated that the ionic liquids were successfully immobilized on the mesoporous molecular sieves. The catalysts could maintain their mesoporous structure and showed good catalytic performance in transesterification. The biodiesel yield was more than 90% under the condition of 30% ILs-loading, methanol to oil molar ratio of 36:1 and temperature at 140 ℃ for 5 h. The beneficial acid environment was created for the active component ILs by introducing Al to MCM-41, which greatly improved the catalytic performance of ILs. The ILs immobilized catalysts exhibited much higher activities in transesterification than the homogeneous ILs, and the ILs immobilized catalyst still yielded about 88% after four cycles.
- catalyst;mesoporous molecular sieves;ionic liquids;immobilize;biodiesel;transesterification
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沈阳化工大学材料科学与工程学院沈阳 110142