Citation: CHEN Man-Sheng, DENG Yi-Fang, CUI Ying, LIU Dong-Cheng, LIANG Fu-Pei. Syntheses, Crystal Structures and Properties of 3D Heteronuclear Mn(Ⅱ)-Sm(Ⅱ) and 2D Homonuclear Sm(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1041-1048. doi: 10.11862/CJIC.2015.130
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Two heteronuclear/homonuclear coordination polymers {[MnSm2(INAIP)4(H2O)4]·2H2O}n (1) and{[Sm(INAIP)(HINAIP)]·2H2O}n (2), where H2INAIP=5-(isonicotinamido)isophthalic acid, were synthesized in a pot and their crystal structures were determined by X-ray diffraction analysis. Complex 1 crystallizes in the triclinic system, space group P1 with a=1.0188(5) nm, b=1.08386(6) nm, c=1.38721(8) nm, V=1.475(14) nm3, Z=1, Dc=1.802 g·cm-3, μ=2.271 mm-1, F(000)=793, Rint=0.0105, R1=0.0512, wR2=0.1319. Complex 2 is of monoclinic system, space group P21/c with a=1.34305(18) nm, b=1.3765(17) nm, c=1.62408(15) nm, V=2.7028(6) nm3, Z=4, Dc=1.861 g·cm-3, μ=2.251 mm-1, F(000)=1500, Rint=0.0514, R1=0.0322, wR2=0.0887. In complex 1, the 2D Sm-carboxylate layer is linked by Mn-Nand Mn-Ointeraction into complicated 3D framework. However, for complex 2, the central Sm(Ⅱ) atom is eight-coordinated by eight carboxylate oxygen atoms. The molecules are connected to form a 2D bilayer structure bridged by 5-(isonicotinamido)isophthalic acid. Furthermore, complex 1 shows adsorption behavior of CO2 with almost no N2 uptake, and the luminescent property of complexes 1 and 2 has also been investigated.
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