Citation: XUE Yun-Shan, XU Yan, DU Hong-Bin. Structural Diversity of Coordination Polymers Built from a Rigid Silicon-Based Tetracarboxylate Linker[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 981-988. doi: 10.11862/CJIC.2015.125 shu

Structural Diversity of Coordination Polymers Built from a Rigid Silicon-Based Tetracarboxylate Linker

XUE Yun-Shan ^1,2 ,
XU Yan ³ ,
DU Hong-Bin ^1,,

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2.
2 School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224051, China;
3.
3 College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China

Corresponding author: DU Hong-Bin,
Received Date: 8 November 2014
Available Online: 13 February 2015
Fund Project: 国家自然科学基金(No.21173153) (No.21173153)四川省科技厅科技支撑项目(2011GZ0035)资助。 (2011GZ0035)

By using a rigid tetrapodal carboxylate linker 4,4',4",4"'-silanetetrayltetrabenzoic acid (H₄L), two open-framework coordination polymers, namely, [CoL][NH₂(CH₃)₂]2·2.25H₂O (1) and [Co₃L₂]H₃O]₂·4DMA (2) (DMA=N, N-Dimethylacetamide), were solvothermally synthesized and structurally characterized. The crystal structure analyses indicate that both compounds crystallize in orthorhombic system. The unit cell parameters for compound 1 are space group Pbca, a=2.2702(2) nm, b=1.4565(7) nm, c=2.8264(7) nm, and for compound 2, space group Pnna, a=2.6982(3) nm, b=2.1882(2) nm, c=1.3821(9) nm. Compound 1 is a 3D framework built on tetrahedral Co units and a 4-connecting ligand Lto give a 4-connected sra structure. Compound 2 is a 3D 2-nodal (4,8)-connected alb network with small 1D channels built from a trinuclear {Co₃(COO)₈} unit and a 4-connected tetrahedral Lligand. The structure diversity of H₄L-based MOFs is discussed.
- coordination polymer;crystal structure;cobalt;ligand
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