Citation: WANG Ji-Xiao, WANG Che, GAO Xue, WANG Zhi-Nan, ZHANG Xiao-Xi, FENG Xiao-Dong, WEI Si-Yue, XING Yong-Heng, SHI Zhan. Copper(Ⅱ) and Cobalt(Ⅱ) Complexes with Arene-Linked Pyrazolyl Methane: Syntheses, Structures and Mimicking Catalytic Activity in Brominating Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 923-929. doi: 10.11862/CJIC.2015.122
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Two complexes [Cu(L1)Cl2]·0.5C2H5OH (1) and Co(L1)Cl2 (2) (L1=1,4-bis((1H-pyrazol-1-yl)methyl)benzene) were designed and synthesized in the anhydrous ethanol system. The spectrum and structural characters of the two complexes were analyzed by elemental analysis, IR spectrum, thermogravimetric analysis, powder X-ray diffraction and single crystal X-ray diffraction analysis. The structural analysis shows that the coordination numbers of metal in complexes 1 and 2 are five and four to form square pyramidal and distorted tetrahedron geometry, respectively, and ligand L1 is in bidentate coordination mode. In addition, complexes 1 and 2 had the mimic catalytic activity during brominating reaction process.
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