Citation: WANG You-He, KOU Long, SUN Hong-Man, LI Yang, XING Wei, YAN Zi-Feng. Controllable Preparation and Characterization of Three-Dimensionally Ordered Macro-Mesoporous Silica Monolith[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 947-953. doi: 10.11862/CJIC.2015.121 shu

Controllable Preparation and Characterization of Three-Dimensionally Ordered Macro-Mesoporous Silica Monolith

WANG You-He ^1,2 ,
KOU Long ² ,
SUN Hong-Man ^1,2 ,
LI Yang ² ,
XING Wei ^1,2 ,
YAN Zi-Feng ^2,,

1.
1 School of Science, China University of Petroleum, Qingdao, Shandong 266555, China;
2.
2 State Key Laboratory for Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, China University of Petroleum, Qingdao, Shandong 266555, China

Corresponding author: YAN Zi-Feng,
Received Date: 23 December 2014
Available Online: 5 February 2015
Fund Project: 大连理工大学精细化工国家重点实验室开放课题基金(No.KF1309)资助项目。 (No.KF1309)

Three-dimensionally(3D) ordered macro-mesoporous silica monolith was prepared via a facile dual-templating technique using self-made poly-(methyl methacrylate) (PMMA) colloidal crystal and triblockcopolymer P123 as templates. The pore structure, surface features of as-prepared samples were characterized by SEM, TEM, low-angle XRD and N₂ adsorption and desorption techniques. The results show that these highly ordered macro-mesoporous silica monoliths have a macropore of about 200 nm, narrowly distributed mesopores (3.5 nm), and high surface area (>550 m²·g^-1). These results also indicate that the 3D ordered macro-mesoporous silica monolith with network or layered structure can be prepared controllably by facilely tailoring and controlling the self-assembly process of PMMA colloidal crystal template. The formation mechanism of the 3D ordered macro-mesoporous composites was also proposed.
- layered structure;dual-templating technique;ordered macro-mesoporous structure;silica monolith
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