Citation: HE Zhong-Bing, LIU Shao-You, YANG Hong-Yun, MIN Zong-Yi, NIE Xin. Sulfur Doped Tin Oxide Nanoparticles: Solid State Synthesis and Performance for Visible-Light Driven Photocatalytic Degradation of Paraquat[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 649-658. doi: 10.11862/CJIC.2015.117
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Sulfur doped tin oxide (S-SnO2) nanoparticles with high visible light-driven activity was synthesized by a facile solid state synthesis approach at low temperature using sodium dodecyl benzene sulfonate (SDBS) as a template. The samples were characterized by XRD, XPS, SEM, UV-Vis, HR-TEM, and FTIR. The doping mechanism and photocatalytic degradation of paraquat under visible light irradiation were investigated. The results show that the SDBS has a significant regulating effect on the surficial structure for both SnO2 and S-SnO2 prepared by solid state synthesis. The S element is successfully incorporated into the lattice of SnO2 with S(Ⅳ) and S(Ⅵ) rather than embeds into the interstice of SnO2 lattice. S-doping enhances the photocatalytic activity of SnO2 due to the presence of a large number of hydroxyls on the surface and S(Ⅵ) in the lattice of SnO2 benefiting the light absorption and effective charge separation, and it follows an order of SnO2 < S-SnO2 < SnO2(SDBS) < S-SnO2(SDBS).
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