Citation: LI Jia-Jia, SONG Shuang, MA Dou, QIAO Li, GU Yi, QIAN Feng-Yun, LI Xia. Syntheses, Crystal Structures and Characterization of Binuclear Lanthanide Complexes with 3-Sulfobenzoate and 2-(4-Pyridyl)imidazole[4,5-f]phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 717-724. doi: 10.11862/CJIC.2015.115
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Taking 3-sulfobenzoate (3-SBA) and 2-(4-pyridyl)imidazole[4,5-f]phenanthroline (4-PDIP) as the ligands, three lanthanide complexes, [Ln2(3-SBA)2(4-PDIP)2(OH)2(H2O)4]·2H2O (Ln=Sm (1), Eu (2), Gd (3)) were obtained by hydrothermal method. The crystal structures were determined by single crystal X-ray diffraction. The three complexes are binuclear molecules. In the complexes, two Ln(Ⅲ) ions are linked by two hydroxyl groups in bridging-bidentate coordination mode. 3-SBA and 4-PDIP ligands are coordinated with Ln(Ⅲ) ions by the chelating bidentate coordination mode. The three-dimensional supramolecular structure is formed through the hydrogen bonds between binuclear molecules. Complexes 1 and 3 display intense broad emission bands at 545 nm and 529 nm, respectively, which correspond to the π*-π transition of the ligands. Complex 2 presents the characteristics emission of Eu(Ⅲ) ion. The narrow emission bands at 579, 592, 612, 650 and 696 nm are attributed to 5D0→7Fj (j=0~4) transitions of the Eu(Ⅲ) ion, respectively. CCDC: 1046171, 1; 1046169, 2; 1046170, 3.
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